First, let's state the chemical reaction:

We can find the number of moles of Cl2 required to produce 0.0923 moles of AlCl3, doing a rule of three: 3 moles of Cl2 reacted produces 2 moles of AlCl3:

The calculation would be:

And the final step is to convert this number of moles to grams. Remember that the molar mass can be calculated using the periodic table, so the molar mass of Cl2 is 70.8 g/mol, and the conversion is:

The answer is that we need 9.770 grams of Cl2 to produce 0.0923 moles of AlCl3.
One mole of an ideal gas will occupy 22.4 liters of volume at STP.
If the only thing that changes is the pressure from 1.00 atm to 2.00 atm, then we know the initial volume, initial pressure, and final pressure. We can use Boyle's law.
Boyle's law: (initial pressure)*(initial volume) = (final pressure)*(final volume)
fill in the knowns
(1.00 atm)*(22.4 liters) = (2.00 atm)(final volume)
divide both sides by 2.00 atm
11.2 liters = final volume
The answer is hydrosphere