Answer:
pKa of the histidine = 9.67
Explanation:
The relation between standard Gibbs energy and equilibrium constant is shown below as:
![\Delta{G^0} =-RT \ln \frac{[His]}{[His+]}](https://tex.z-dn.net/?f=%5CDelta%7BG%5E0%7D%20%3D-RT%20%5Cln%20%5Cfrac%7B%5BHis%5D%7D%7B%5BHis%2B%5D%7D)
R is Gas constant having value = 0.008314 kJ / K mol
Given temperature, T = 293 K
Given, 
So, Applying in the equation as:-
![15\ kJ/mol=-0.008314\ kJ/Kmol\times 293\ K\times \ln \frac{[His]}{[His+]}](https://tex.z-dn.net/?f=15%5C%20kJ%2Fmol%3D-0.008314%5C%20kJ%2FKmol%5Ctimes%20293%5C%20K%5Ctimes%20%5Cln%20%5Cfrac%7B%5BHis%5D%7D%7B%5BHis%2B%5D%7D)
Thus,
![\frac{[His]}{[His+]}=e^{\frac{15}{-0.008314\times 293}](https://tex.z-dn.net/?f=%5Cfrac%7B%5BHis%5D%7D%7B%5BHis%2B%5D%7D%3De%5E%7B%5Cfrac%7B15%7D%7B-0.008314%5Ctimes%20293%7D)
![\frac{[His]}{[His+]}=0.00211](https://tex.z-dn.net/?f=%5Cfrac%7B%5BHis%5D%7D%7B%5BHis%2B%5D%7D%3D0.00211)
Also, considering:-
![pH=pKa+log\frac{[His]}{[His+]}](https://tex.z-dn.net/?f=pH%3DpKa%2Blog%5Cfrac%7B%5BHis%5D%7D%7B%5BHis%2B%5D%7D)
Given that:- pH = 7.0
So, 
<u>pKa of the histidine = 9.67</u>
The general equation for radioactive decay is;
N = N₀e^(-λt)
x - decay constant (λ) - rate of decay
t- time
N - amount remaining after t days , since we are calculating the half life, amount of time it takes for the substance to to be half its original value, its N₀/2
N₀ - amount initially present
substituting the values
N₀/2 = N₀e^(-0.081t)
0.5 = e^(-0.081t)
ln (0.5) = -0.081t
-0.693 = -0.081t
t = 0.693 / 0.081
= 8.55
half life of substance is 8.55 days
Answer:
4 - 1 - 3 - 2 - 6 - 5
Explanation:
During an engineering process, first, we need to identify the problem, or the need because the process only will occur because of some need. Then, it's necessary to know as much as possible about the problem and the things that already exist or already were tested to solve it. Knowing the background will make the work easy.
After that, it's necessary to plan the things we'll do, knowing the costs, the time needed for activities, how many people will be necessary for each step, etc. It's really important to make a plan. Then, do the work, following the plan. Thus, the process must be tested. During the test of the results, some problems must be found, so it's time to evaluate and redesign the process, to solve these problems found.
Explanation
NaCl: Ionic crystal lattice forces
Hg: Metallic bonding
CO₂: London dispersion forces
CH₄: London dispersion forces
Li₂O: Ionic crystal lattice forces
Ag: Metallic bonds
Ionic crystal lattice forces are strong electrostatic force of attraction between oppositely charged ions arranged into a crystal lattice of ionic compound. NaCl and Li₂O are ionic compounds
London dispersion forces holds the molecules of carbon dioxide and methane. They are weak attractions found between non-polar (and polar) molecules.
Metallic bonds exists between Mercury and Gold atoms. This is due to sea of electrons present.
