Answer:
Q14: 17,140 g = 17.14 kg.
Q16: 504 J.
Explanation:
<u><em>Q14:</em></u>
- To solve this problem, we can use the relation:
<em>Q = m.c.ΔT,</em>
where, Q is the amount of heat absorbed by ice (Q = 3600 x 10³ J).
m is the mass of the ice (m = ??? g).
c is the specific heat of the ice (c of ice = 2.1 J/g.°C).
ΔT is the difference between the initial and final temperature (ΔT = final T - initial T = 100.0°C - 0.0°C = 100.0°C).
∵ Q = m.c.ΔT
∴ (3600 x 10³ J) = m.(2.1 J/g.°C).(100.0°C)
∴ m = (3600 x 10³ J)/(2.1 J/g.°C).(100.0°C) = 17,140 g = 17.14 kg.
<u><em>Q16:</em></u>
- To solve this problem, we can use the relation:
<em>Q = m.c.ΔT,</em>
where, Q is the amount of heat absorbed by ice (Q = ??? J).
m is the mass of the ice (m = 12.0 g).
c is the specific heat of the ice (c of ice = 2.1 J/g.°C).
ΔT is the difference between the initial and final temperature (ΔT = final T - initial T = 0.0°C - (-20.0°C) = 20.0°C).
∴ Q = m.c.ΔT = (12.0 g)(2.1 J/g.°C)(20.0°C) = 504 J.
To determine which order of the reaction it is, first we need to calculate the rate of change of moles.
the data is as follows
time 0 40 80 120 160
moles 0.100 0.067 0.045 0.030 0.020
Q1)
for the first 40 s change of moles ;
= -d[A] / t
= - (0.067-0.100)/40s
= 8.25 x 10⁻⁴ mol/s
for the next 40 s
= -(0.045-0.067)/40
= 5.5 x 10⁻⁴ mol/s
the 40 s after that
= -(0.030-0.045)/40 s
= 3.75 x 10⁻⁴ mol/s
k - rate constant
and A is the only reactant that affects the rate of the reaction
rate = k [A]ᵇ
8.25 × 10⁻⁴ mol/s = k [0.100 mol]ᵇ ----1
5.5 x 10⁻⁴ mol/s = k [0.067 mol]ᵇ -----2
divide the 2nd equation by the 1st equation
1.5 = [1.49]ᵇ
b is almost equal to 1
Therefore this is a first order reaction
Q2)
to find out the rate constant(k), we have to first state the equation for a first order reaction.
rate = k[A]ᵇ
As A is the only reactant thats considered for the rate equation.
Since this is a first order reaction,
b = 1
therefore the reaction is
rate = k[A]
substituting the values,
8.25 x 10⁻⁴ mol/s = k [0.100 mol]
k = 8.25 x 10⁻⁴ mol/s /0.100mol
= 8.25 x 10⁻³ s⁻¹
Answer:
Coefficients represents no of moles while subscripts represent no of atoms.
PH + pOH = 14
pH = 14 - pOH
pH = 14 - 8.7
pH = 5,3
This solution is <u>acidic</u>.
If pH<7 - acidic
If pH=7 - neutral
If pH>7 - basic
Equilibrium occurs when the rate of the forward reaction is the same as the rate of the reverse reaction. This doesn't necessarily mean the concentrations or pressure are the same on both sides of the equation, only the rates are the same
