Answer: b.
is positive and
is positive.
Explanation:-
As the temperature of the pack drops, the energy has been absorbed from the pack for dissolution of
in water. Thus as the energy has been absorbed in the reaction, the reaction is endothermic and the change in enthalpy i.e.
is positive.
The entropy is the measure of degree of randomness. The entropy increases when the randomness increases and the entropy decreases when the randomness decreases. When a substance dissolves in water, it dissociate into ions and hence the randomness increases thus the change in entropy i.e.
is positive.
Answer:
balanced in ACID not BASE
Cr2O7^2-(aq) +3Hg(l) +14 H^1+ ----> 3Hg^2+ + 2Cr^3+(aq) + 7H2O
Answer
Cr2O7^2-(aq) +3Hg(l) +14 H^1+ ----> 3Hg^2+ + 2Cr^3+(aq) + 7H2O
Explanation:
Cr2O7^2-(aq) + Hg(l) ----> Hg^2+(aqH) + Cr^3+(aq)
add H^1+ (acid) to capture the O and make 7 water molecules
Cr2O7^2-(aq) + Hg(l) + H^1+ ----> Hg^2+(aqH) + Cr^3+(aq) + 7H2O
Cr goes from +6 to +3 by gaining 3 e
Hg goes from 0 to +2 by losing 2 e
we need 3 Hg for every 2 Cr
so
Cr2O7^2-(aq) +3Hg(l) +14 H^1+ ----> 3Hg^2+ + 2Cr^3+(aq) + 7H2O
2 Cr on the right and left
Net 12 positive charges on the right and the left
3 Hg on the right and left
14 H on the right and left
the equation is balanced
we cannot balance the equation in a basic solution with OH^1-
we have plenty of O in the dichromate ion. we need to convert it to water which take free H^1+ from the acid
According to the statement
2.12 x 10^4 lbs pounds of CaCO₃ are needed to neutralize this acid
<h3>What is neutralization?</h3>
A chemical reaction in which an acid and a base react quantitatively with each other is known as neutralization or neutralization. In a water reaction, neutralization ensures that there is no excess of hydrogen or hydroxide ions in the solution.
<h3>According to the given information:</h3>
The equation of the neutralization reaction between H2SO4 and CaCO3.
CaCO3 + H2SO4 → CaSO4 + H2CO3
H2CO3 dissociate to water and carbon dioxide.
CaCO3 + H2SO4 → CaSO4 + H2O + CO2
Now solving for the mass of CaCO3 needed to neutralize the acid.
mass of CaCO3 = 9460 Kg H2SO4 × 

= 21284.56606
mass of CaCO3 = 2.12 x 10^4 lbs
2.12 x 10^4 lbs pounds of CaCO₃ are needed to neutralize this acid.
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Answer : At constant pressure work is done by the system on the surroundings.
Explanation :
Work done : Any quantity that flows across the boundary of a system during a change in its state and it completely convertible into the lifting of a weight in the surroundings.
Formula for work done is:

Sign convention :
- When volume expand then system work that means work done by the system.
w = (-ve)
- When volume compress then surrounding work that means work done on the system.
w = (+ve)
The given reaction is:

This is a evaporation process in which phase changes from liquid state to gaseous state at constant temperature.
At constant pressure, work depends only on volume.
In evaporation process, the volume expand that means work is done by the system on the surroundings.
Sign convention is, w = (-ve)
Thus, at constant pressure work is done by the system on the surroundings.
Explanation:
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