First, recognize that this is an elimination reaction in which hydroxide must leave and a double bond must form in its place. It is likely an E2 reaction. Here is an efficient mechanism:
1) Pre-reaction: Protonate the -OH to make it a good leaving group, water. H2SO4 or any strong H+ donor works. The water is positively charged but still connected to the compound.
2) E2: Use a sterically hindered base, such as tert-butoxide (tButO-) to abstract the hydrogen from the secondary carbon. [You want a sterically hindered base because a strong, non-sterically hindered base could also abstract a hydrogen from one of the two methyl groups on the tertiary carbon, and that leads to unwanted products, which is not efficient]. As the proton of hydrogen is abstracted, water leaves at the same time, creating an intermediate tertiary carbocation, and the 2 electrons in the C-H bond immediately are used to make a double bond towards the partial positive charge.
In the products we see the major product and water, as expected. Even though you have an intermediate, remember that an E2 mechanism technically happens in one step after -OH protonation.
Barium, it's an earthy alkaline metal it's atomic number is 56
5.167g of calcium chloride is dissolved in 101.0mL of water in a calorimeter whose calorimeter constant is 15.3J/°C. The temperature rises from 18.4°C to 27.2 ...
Answer:
The mass of
4.6
×
10
24
atoms of silver is approximately 820 g.
Explanation:
In order to determine the mass of a given number of atoms of an element, identify the equalities between moles of the element and atoms of the element, and between moles of the element and its molar mass.
1
mole atoms Ag=6.022xx10
23
atoms Ag
Molar mass of Ag =#"107.87 g/mol"#
Multiply the given atoms of silver by
1
mol Ag
6.022
×
23
atoms Ag
. Then multiply times the molar mass of silver.
4.6
×
10
24
atoms Ag
×
1
mol Ag
6.022
×
10
23
atoms Ag
×
107.87
g Ag
1
mol Ag
=
820 g Ag
