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anyanavicka [17]
3 years ago
7

How do transmittance, absorbance, and molar absorptivity differ? Which one is proportional to concentration?

Chemistry
1 answer:
Komok [63]3 years ago
4 0

Answer:

The transmittance is the amount of energy that a body goes through in a certain amount of time without being absorbed and the absorbance is the amount of light that is absorbed by a solution.

There is no difference between absorptivity and molar absorptivity because the two terms express the same idea, because molar absorptivity is the absorbance of a solution per unit path length and concentration, so that the absorbance is proportional to concentration.

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Explanation:

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You are cutting each concentration in half, so

\dfrac{\text{[A]}_{2}}{\text{[A]}_{1}} = \dfrac{1}{2}\text{ and }\dfrac{\text{[B]}_{2}}{\text{[B]}_{1}}= \dfrac{1}{2}

Then,

\dfrac{\text{rate}_{2}}{\text{rate}_{1}} = \left (\dfrac{1}{2}\right ) \left (\dfrac{1}{2}\right )^{2} = \dfrac{1}{2}\times\dfrac{1}{4} = \dfrac{1}{8}\\\\\text{rate}_{2} = \dfrac{1}{8}\times \text{rate}_{1}= \dfrac{1}{8}\times \text{0.0080 mol$\cdot$L$^{-1}$s$^{-1}$} = \textbf{0.0010 mol$\cdot$L$^{-1}$s$^{-1}$}\\\\\text{The new rate is $\large \boxed{\textbf{0.0010 mol$\cdot$L$^\mathbf{{-1}}$s$^{\mathbf{-1}}$}}$}

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