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Nataly [62]
4 years ago
13

Consider the mechanism. Step 1: A+B↽−−⇀CA+B↽−−⇀C equilibrium Step 2: C+A⟶DC+A⟶D slow Overall: 2A+B⟶D2A+B⟶D Determine the rate la

w for the overall reaction, where the overall rate constant is represented as ????.
Chemistry
1 answer:
tatuchka [14]4 years ago
5 0

Answer:

rate = k[A][B] where k = k₂K

Explanation:

Your mechanism is a slow step with a prior equilibrium:

\begin{array}{rrcl}\text{Step 1}:& \text{A + B} & \xrightarrow [k_{-1}]{k_{1}} & \text{C}\\\text{Step 2}: & \text{C + A} & \xrightarrow [ ]{k_{2}} & \text{D}\\\text{Overall}: & \text{2A + B} & \longrightarrow \, & \text{D}\\\end{array}

(The arrow in Step 1 should be equilibrium arrows).

1. Write the rate equations:

-\dfrac{\text{d[A]}}{\text{d}t} = -\dfrac{\text{d[B]}}{\text{d}t} = -k_{1}[\text{A}][\text{B}] + k_{1}[\text{C}]\\\\\dfrac{\text{d[C]}}{\text{d}t} = k_{1}[\text{A}][\text{B}] - k_{2}[\text{C}]\\\\\dfrac{\text{d[D]}}{\text{d}t} = k_{2}[\text{C}]

2. Derive the rate law

Assume k₋₁ ≫ k₂.  

Then, in effect, we have an equilibrium that is only slightly disturbed by C slowly reacting to form D.  

In an equilibrium, the forward and reverse rates are equal:

k₁[A][B] = k₋₁[C]

[C] = (k₁/k₋₁)[A][B] = K[A][B] (K is the equilibrium constant)

rate = d[D]/dt = k₂[C] = k₂K[A][B] = k[A][B]

The rate law is  

rate = k[A][B] where k = k₂K

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Calculate the final concentration of each of the following:
kkurt [141]

Answer:

1. 2 M

2. 2 M

Explanation:

1. Determination of the final concentration.

Initial Volume (V₁) = 2 L

Initial concentration (C₁) = 6 M

Final volume (V₂) = 6 L

Final concentration (C₂) =?

The final concentration can be obtained as follow:

C₁V₁ = C₂V₂

6 × 2 = C₂ × 6

12 = C₂ × 6

Divide both side by 6

C₂ = 12 / 6

C₂ = 2 M

Therefore, the final concentration of the solution is 2 M

2. Determination of the final concentration.

Initial Volume (V₁) = 0.5 L

Initial concentration (C₁) = 12 M

Final volume (V₂) = 3 L

Final concentration (C₂) =?

The final concentration can be obtained as follow:

C₁V₁ = C₂V₂

12 × 0.5 = C₂ × 3

6 = C₂ × 3

Divide both side by 3

C₂ = 6 / 3

C₂ = 2 M

Therefore, the final concentration of the solution is 2 M

7 0
3 years ago
What is the correct way to write 1,550,000,000 in scientific notation
aliina [53]
It would be 1.55x10 to the 9th
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6 0
3 years ago
K2so4 is a strong electrolyte. determine the concentration of each of the individual ions in a 0.450 m k2so4 solution.
amid [387]

<em>Answer:</em>

  • Conc. of K+ ions = 0.90 M
  • Coc. of SO4∧-2 = 0.45 M

<em>Explanation:</em>

<em>Data Given:</em>

Conc. of H2SO4 = 0.450

As sulphoric acid is a strong electrolyte, it completely dissociate into ions.

H2SO4 ⇆   2K+   +   SO4∧-2

.450 M K2SO4 means that there is .450 mols of K2SO4 in every liter of solution.

                      K2SO4  :  K+                                          K2SO4  : SO4∧-2

                          1      =     2                                                   1     =    1

                     0.450   =   2× 0.450 = 0.90                     0.450 =  0.450×1 = 0.450

<em> Result:</em>

Conc. of potassium ion will be 0.90M    

Coc. of sulphate ions will be 0.45 M

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3 years ago
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tino4ka555 [31]
16287.50 I think? I just googled it though so I’m not sure if it’s correct.
6 0
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In which solid sound travel faster than any others.ans me pls​
Crank

Answer:

THE SOUND TRAVELS FASTER IN SOLIDS BECAUSE ITS MOLECULES ARE CLOSE TO EACH OTHER WHILE LIQUIDS MOLECULES ARE NOT TIGHT AS OF SOLID AND IN GAS THE MOLECULES ARE FREE

5 0
3 years ago
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