Answer:
[HF]₀ = 0.125M
Explanation:
NaOH + HF => NaF + H₂O
Adding 20ml of 0.200M NaOH into 25ml of HF solution neutralizes 0.004 mole of HF leaving 0.004 mole NaF in 0.045L with 0.001M H⁺ at pH = 3. This is 0.089M NaF and 0.001M HF remaining.
=> 45ml of solution with pH = 3 and contains 0.089M NaF from titration becomes a common ion problem.
HF ⇄ H⁺ + F⁻
C(eq) [HF] 10⁻³M 0.089M (<= soln after adding 20ml 0.200M NaOH)
Ka = [H⁺][F⁻]/[HF]₀ => [HF]₀ = [H⁺][F⁻]/Ka
[HF]₀ = (0.001)(0.089)/(7.1 x 10⁻⁴) M = 0.125M
Answer:
they had killed other animals
A way to explain it is that back then all the continents were together but soon after drifted apart the were in the same place sort of put they drifted apart so that's sorta what happened. Hope that helps a little
