The answer is 23.5° but I guess 23° is closest
The molarity of formic acid is 100 mM or 
. The dissociation reaction of formic acid is as follows:
The expression for dissociation constant of the reaction will be:
![K_{a}=\frac{[HCOO^{-}][H^{+}]}{[HCOOH]}](https://tex.z-dn.net/?f=K_%7Ba%7D%3D%5Cfrac%7B%5BHCOO%5E%7B-%7D%5D%5BH%5E%7B%2B%7D%5D%7D%7B%5BHCOOH%5D%7D)
Rearranging,
![[HCOO^{-}]=\frac{K_{a}[HCOOH]}{[H^{+}]}](https://tex.z-dn.net/?f=%5BHCOO%5E%7B-%7D%5D%3D%5Cfrac%7BK_%7Ba%7D%5BHCOOH%5D%7D%7B%5BH%5E%7B%2B%7D%5D%7D)
Here, pH of solution is 4.15 thus, concentration of hydrogen ion will be:
![[H^{+}]=10^{-pH}=10^{-4.15}=7.08\times 10^{-5}M](https://tex.z-dn.net/?f=%5BH%5E%7B%2B%7D%5D%3D10%5E%7B-pH%7D%3D10%5E%7B-4.15%7D%3D7.08%5Ctimes%2010%5E%7B-5%7DM)
Similarly, 
thus,
Putting the values,
![[HCOO^{-}]=\frac{(1.78\times 10^{-4}M)(100\times 10^{-3}M)}{(7.08\times 10^{-5}M}=0.2511 M](https://tex.z-dn.net/?f=%5BHCOO%5E%7B-%7D%5D%3D%5Cfrac%7B%281.78%5Ctimes%2010%5E%7B-4%7DM%29%28100%5Ctimes%2010%5E%7B-3%7DM%29%7D%7B%287.08%5Ctimes%2010%5E%7B-5%7DM%7D%3D0.2511%20M)
Therefore, the concentration of formate will be 0.2511 M.
Pluto is a dwarf planet, but one of the largest known members, in the Kuiper belt.
The Kuiper Belt extends between 30 AU and 55 AU from the Sun
(1 AU = 1.5 × 10^8 km = distance from Earth to Sun).
Pluto's orbit is highly elliptical. It ranges from 30 AU to 50 AU. When Pluto is closest to the Sun, it is inside the orbit of Neptune (30 AU).
Astronomers class Pluto as a <em>resonant Kuiper belt object</em> (KBO). Because it gets so close to Neptune, its orbit is in <em>resonance</em> with that of Neptune. Pluto makes two orbits for every three of Neptune.
Answer: d. both (b) and (c)
Explanation:
Atoms are too small to be seen on microscopes, so we model them based on theories.
