Answer:
Heating the system
Explanation:
According to the principle of Le Chatelier, for a system at equilibrium, a specific disturbance would make the equilibrium shift toward the direction which minimizes such a disturbance.
Since we wish to shift the equilibrium to the left, this means we wish to increase the concentration of products, as an excess in their concentration would make the products react and produce more reactants in order to lower the excess concentration of products.
Since heat is also a product, an increase in heat would shift the equilibrium toward the left, as this would consume the excess of heat by producing the reactants.
Answer:
Carbon monoxide is a very important industrial compound. In the form of producer gas or water gas.
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Answers and Explanation:
a)- The chemical equation for the corresponden equilibrium of Ka1 is:
2. HNO2(aq)⇌H+(aq)+NO−2
Because Ka1 correspond to a dissociation equilibrium. Nitrous acid (HNO₂) losses a proton (H⁺) and gives the monovalent anion NO₂⁻.
b)- The relation between Ka and the free energy change (ΔG) is given by the following equation:
ΔG= ΔGº + RT ln Q
Where T is the temperature (T= 25ºc= 298 K) and R is the gases constant (8.314 J/K.mol)
At the equilibrium: ΔG=0 and Q= Ka. So, we can calculate ΔGº by introducing the value of Ka:
⇒ 0 = ΔGº + RT ln Ka
ΔGº= - RT ln Ka
ΔGº= -8.314 J/K.mol x 298 K x ln (4.5 10⁻⁴)
ΔGº= 19092.8 J/mol
c)- According to the previous demonstation, at equilibrium ΔG= 0.
d)- In a non-equilibrium condition, we have Q which is calculated with the concentrations of products and reactions in a non equilibrium state:
ΔG= ΔGº + RT ln Q
Q= ((H⁺) (NO₂⁻))/(HNO₂)
Q= ( (5.9 10⁻² M) x (6.7 10⁻⁴ M) ) / (0.21 M)
Q= 1.88 10⁻⁴
We know that ΔGº= 19092.8 J/mol, so:
ΔG= ΔGº + RT ln Q
ΔG= 19092.8 J/mol + (8.314 J/K.mol x 298 K x ln (1.88 10⁻⁴)
ΔG= -2162.4 J/mol
Notice that ΔG<0, so the process is spontaneous in that direction.
False
Although we use many of their ideas to describe atoms today, such as the existence of a tiny, dense nucleus in an atom (proposed by Rutherford), or the notion that all atoms of an element are identical (proposed by Dalton), some of their ideas have been rejected by the modern theory of the atom.
For example, Thompson came up with the plum pudding model to describe an atom, which resembled a sphere of positive charge with electrons embedded in it. We know now, however, that atoms are mostly empty space with a tiny, dense nucleus.
Another example is Dalton's atomic theory, which stated that atoms are indivisible particles. However, this was disproved by the discovery of subatomic particles.
Answer:
1. How do metals and non-metals react with acids?
Ans : Non metals does not react with acids while metals react with acids and produce hydrogen gas that burns with a 'pop'sound.
2. Write and explain the chemical equation for the reaction of magnesium with sulphuric acid and aluminium with hydrochloric acid.
Magnesium + sulphuric acid = Hydrogen + salt
Mg(s) + H2SO4 (aq) MgSO 4(aq) +H2 (g)
Aluminium + Hydrochloric acid = Hydrogen + Aluminium chloride
2Al(s)+6HCl(aq)→2AlCl3(aq)+3H2(g)
