We have to know whether F₂²⁺ is paramagnetic or diamagnetic.
F₂²⁺ is paramagnetic.
If number of unpaired electron in any species is equal to zero, the species is diamagnetic and the species contains unpaired electrons, then the species is paramagnetic.
The magnetic property can be explained using molecular orbital theory.
Total number of electron present in F₂²⁺ is equal to 16 (i.e, 9+9-2). From the molecular orbital electronic configuration, number of electrons present in pi orbitals present is equal to 2.
So, F₂²⁺ is paramagnetic.
f it is solid iron, use the density to get the mass. D x V = mass
Use the mass to find the moles of Fe. Mass/atomic mass = moles
Moles x Avogadro's number will give you the particles, assuming that you mean atoms.

the way that you get 66 is by adding he atomic mass unit of each atom in the formula. so N2 is 14 + 14 H4 is 1 * 4 and 03 is 16 * 3