D) because both reactions are occurring at the same rate. They are not equal but their concentrations are constant.
For equal moles of gas, temperature can be calculated from ideal gas equation as follows:
P×V=n×R×T ...... (1)
Initial volume, temperature and pressure of gas is 3.25 L, 297.5 K and 2.4 atm respectively.
2.4 atm ×3.25 L=n×R×297.5 K
Rearranging,
n\times R=0.0262 atm L/K
Similarly at final pressure and volume from equation (1),
1.5 atm ×4.25 L=n×R×T
Putting the value of n×R in above equation,
1.5 atm ×4.25 L=0.0262 (atm L/K)×T
Thus, T=243.32 K
The answer is the second choice.