Answer:
1.9 × 10² g NaN₃
1.5 g/L
Explanation:
Step 1: Write the balanced decomposition equation
2 NaN₃(s) ⇒ 2 Na(s) + 3 N₂(g)
Step 2: Calculate the moles of N₂ formed
N₂ occupies a 80.0 L bag at 1.3 atm and 27 °C (300 K). We will calculate the moles of N₂ using the ideal gas equation.
P × V = n × R × T
n = P × V / R × T
n = 1.3 atm × 80.0 L / (0.0821 atm.L/mol.K) × 300 K = 4.2 mol
We can also calculate the mass of nitrogen using the molar mass (M) 28.01 g/mol.
4.2 mol × 28.01 g/mol = 1.2 × 10² g
Step 3: Calculate the mass of NaN₃ needed to form 1.2 × 10² g of N₂
The mass ratio of NaN₃ to N₂ is 130.02:84.03.
1.2 × 10² g N₂ × 130.02 g NaN₃/84.03 g N₂ = 1.9 × 10² g NaN₃
Step 4: Calculate the density of N₂
We will use the following expression.
ρ = P × M / R × T
ρ = 1.3 atm × 28.01 g/mol / (0.0821 atm.L/mol.K) × 300 K = 1.5 g/L
Nitrogen (N2) and hydrogen (H2) gases react to form ammonia, which requires -99.4 J/K of standard entropy (ΔS°).
What is standard entropy?
The difference between the total standard entropies of the reaction mixture and the summation of the standard entropies of the outputs is the standard entropy change. Each entropy in the balanced equation needs to be compounded by its coefficient, as shown by the letter "n."
Calculation:
Balancing the given reaction following-
1/2 N₂(g) + 3/2 H₂ (g)→ NH₃ (g)
ΔS° = [1 mol x S° (NH₃)g] - [1/2 mol x S° (N₂)g] - [3/2 mol x S°(H₂)g]
Here S° = standard entropy of the system
Insert into the aforementioned equation all the typical entropy values found in the literature:
ΔS° = [1 mol x 192.45 J/mol.K] - [1/2 mol x 191.61 J/mol.K] - [3/2 mol x 130.684 J/mol.K]
⇒ΔS° = - 99.4 J/K
Therefore, the standard entropy, ΔS° is -99.4 J/K.
Learn more about standard entropy here:
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I would say C. Permable
Google def.(of a material or membrane) allowing liquids or gases to pass through it.
"a frog's skin is permeable to water
Porous- (of a rock or other material) having minute spaces or holes through which liquid or air may pass
The tilt of the Earth on its axis is what causes the seasons.