Answer:
1. 2.510kJ
2. Q = 1.5 kJ
Explanation:
Hello there!
In this case, according to the given information for this calorimetry problem, we can proceed as follows:
1. Here, we consider the following equivalence statement for converting from calories to joules and from joules to kilojoules:

Then, we perform the conversion as follows:

2. Here, we use the general heat equation:

And we plug in the given mass, specific heat and initial and final temperature to obtain:

Regards!
I believe the answer is C
Answer:
The correct answer is entropy change of the surrounding plus the entropy change of the system must be positive.
Explanation:
The term entropy is a state function.Entropy can be defined as the disorder or randomness of the molecules in a system.
A spontaneous reaction is a type of reaction which deals with the release of free energy.The change of free energy in case of spontaneous reaction is always negative.
According to the second law of thermodynamics a spontaneous reaction will occur in a system if the total entropy of both system and surrounding increases during the reaction.
Answer:
I think the answer would be option d.
hope it helps.