HBr and HF are both monoprotic Arrhenius acids—that is, in aqueous solution, they dissociate and ionize to give hydrogen ions. A strong acid ionizes completely; a weak acid ionizes partially.
In this case, HBr, being a strong acid, would ionize completely in water to yield H+ and Br- ions. However, HF, being a weak acid, would ionize only to a limited extent: some of the HF molecules will ionize into H+ and F- ions, but most of the HF will remain undissociated.
pH is, by definition, a measurement of the concentration of hydrogen ions in solution (pH = -log[H+]). A higher concentration of hydrogen ions gives a lower pH, while a lower concentration of hydrogen ions gives a higher pH. At 25 °C, a pH of 7 indicates a neutral solution; a pH less than 7 indicates an acidic solution; and a pH greater than 7 indicates a basic solution.
If we have equal concentrations of HBr and HF, then the HBr solution will have a greater concentration of hydrogen ions in solution than the HF solution. Consequently, the pH of the HBr solution will be less than the pH of the HF solution.
Choice A is incorrect: Strong acids like HBr dissociate completely, not partially.
Choice B is incorrect: While the initial concentration of HBr and HF are the same, the H+ concentration in the HBr solution is greater. Since pH is a function of H+ concentration, the pH of the two solutions cannot be the same.
Choice C is correct: A greater H+ concentration gives a lower pH value. The HBr solution has the greater H+ concentration. Thus, the pH of the HBr solution would be less than that of the HF solution.
Choice D is incorrect for the reason why choice C is correct.
When the pressure of an atmosphere occurs because of the force exerted so at the time of the higher altitudes, the air mass i.e. above the earth should be less as the air is attracted towards surface of an earth because of the gravity and air contains the mass that shows near the surface area so automatically the air density reduced due to which the mass also decreased
When diluting solutions from concentrated solutions the following formula can be used c1v1 = c2v2 where c1 is concentration and v1 is volume of the concentrated solution and c2 is concentration and v2 is volume of the diluted solution to be prepared substituting these values 0.0813 M x 16.5 mL = 0.0200 M x V V = 67.1 mL the volume of the diluted solution prepared is 67.1 mL. the volume of water that should be added to get a final volume of 67.1 mL is (67.1 - 16.5 ) = 50.6 mL a volume fo 50.6 mL should be added
