Answer :
(1) pH = 1.27
(2) pH = 13.35
(3) The given solution is not a buffer.
Explanation :
<u>(1) 53.1 mM HCl</u>
Concentration of HCl = 
As HCl is a strong acid. So, it dissociates completely to give hydrogen ion and chloride ion.
So, Concentration of hydrogen ion= 
pH : It is defined as the negative logarithm of hydrogen ion concentration.
![pH=-\log [H^+]](https://tex.z-dn.net/?f=pH%3D-%5Clog%20%5BH%5E%2B%5D)


<u>(2) 0.223 M KOH</u>
Concentration of KOH = 0.223 M
As KOH is a strong base. So, it dissociates completely to give hydroxide ion and potassium ion.
So, Concentration of hydroxide ion= 0.223 M
Now we have to calculate the pOH.
![pOH=-\log [OH^-]](https://tex.z-dn.net/?f=pOH%3D-%5Clog%20%5BOH%5E-%5D)


Now we have to calculate the pH.

<u>(3) 53.1 mM HCl + 0.223 M KOH</u>
Buffer : It is defined as a solution that maintain the pH of the solution by adding the small amount of acid or a base.
It is not a buffer because HCl is a strong acid and KOH is a strong base. Both dissociates completely.
As we know that the pH of strong acid and strong base solution is always 7.
So, the given solution is not a buffer.
Answer:
pKa = 3.675
Explanation:
∴ <em>C</em> X-281 = 0.079 M
∴ pH = 2.40
let X-281 a weak acid ( HA ):
∴ HA ↔ H+ + A-
⇒ Ka = [H+] * [A-] / [HA]
mass balance:
⇒<em> C</em> HA = 0.079 M = [HA] + [A-]
⇒ [HA] = 0.079 - [A-]
charge balance:
⇒ [H+] = [A-] + [OH-]... [OH-] is negligible; it comes from to water
⇒ [H+] = [A-]
∴ pH = - log [H+] = 2.40
⇒ [H+] = 3.981 E-3 M
replacing in Ka:
⇒ Ka = [H+]² / ( 0.079 - [H+] )
⇒ Ka = ( 3.981 E-3 )² / ( 0.079 - 3.981 E-3 )
⇒ Ka = 2.113 E-4
⇒ pKa = - Log ( 2.113 E-4 )
⇒ pKa = 3.675
Answer:
17.5moles
Explanation:
The number of moles in a substance can be calculated by using the formula;
Number of moles (n) = mass (m) ÷ molar mass (MM)
According to this question, mass of ammonia (NH3) = 297g
Molar Mass of NH3 = 14 + 1(3)
= 17g/mol
n = 297/17
n = 17.47
Number of moles of NH3 = 17.5moles
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