1)
<span>m(NaCl) = 1.95 g
V(H2O) = 250mL
M(NaCl) = </span><span>58.5 g/mole
Since waters density value is 1g/mL, it can be assumed that volume and mass of water are same values:
</span>V(H2O) = 250ml = 250g = 0.25 kg<span>
</span><span>molality of NaCl:
</span><span>
n(NaCl)=m/M=1.95/58.5= 0.033 mole
</span>molality b(NaCl)=n(NaCl) / V (H2O)= 0.033/0.25 = 0.132 mol/kg
<span>
milimolality of NaOH = 0.132/0,001 = 132 mmole/kg
</span>
milliosmolality of NaOH = milimolality x N of ions formed in dissociation
Since NaCl dissociates into 2 ions in solution:
<span>
</span>milliosmolality of NaOH = 132 x 2 = 264 osmol<span>es/kg
</span>
2)
m(gl) = 9 g
V(H2O) = 250mL
M(NaCl) = 180 g/mole
Since waters density value is 1g/mL, it can be assumed that volume and mass of water are same values:
V(H2O) = 250ml = 250g = 0.25 kg
molality of glucose:
n(gl)=m/M=9/180= 0.05 mole
molality b(gl)=n(gl) / V (H2O)= 0.05/0.25 = 0.2 mol/kg
milimolality of glucose = 0.132/0,001 = 200 mmole/kg
milliosmolality of glucose = milimolality x N of ions formed in dissociation
Since glucose does not dissociate, milimolality and milliosmolality are same:
milliosmolality of glucose = 200 osmoles/kg
3)
The osmosis represents the diffusion of solvent molecules through a semi-permeable membrane that allows passage solvent molecules but does not to the dissolved substance molecule. The osmosis occurs when the concentrations of the solution on both sides of the membrane are different. Since the semi-permeable membrane only permeates the solvent molecules, but not the particles of the dissolved substance, it occurs the solvent diffusion through the membrane, i.e. the solvent molecules pass through the membrane to equalize the concentration on both sides of the membrane. Solvents molecules move from the middle with a lower concentration in the middle with a higher concentration of dissolved substances.
In our case, osmosis will occur because the concentration of NaCl solution and the concentration of glucose solution do not have same values. Osmosis will occur in the direction of glucose solution because it has a lower concentration.
Answer: The coefficients are 2, 2 and 1.
Explanation: According to the law of conservation of mass, mass can neither be created nor be destroyed. Thus the mass of products has to be equal to the mass of reactants.
The number of atoms of each element has to be same on reactant and product side. Thus chemical equations are balanced.
The balanced chemical equation for the given reaction is:
2H2o➡️2h2+o2
Energy= 2381 joules
heat= Mass(kg) *change in temperature(K) * Cp
2381=0.155*(15)*Cp
Cp=1024 J/kg K
Answer:
ΔG°rxn = +50.8 kJ/mol
Explanation:
It is possible to obtain ΔG°rxn of a reaction at certain temperature from ΔH°rxn and S°rxn, thus:
<em>ΔG°rxn = ΔH°rxn - T×S°rxn (1)</em>
In the reaction:
2 HNO3(aq) + NO(g) → 3 NO2(g) + H2O(l)
ΔH°rxn = 3×ΔHfNO2 + ΔHfH2O - (2×ΔHfHNO3 + ΔHfNO)
ΔH°rxn = 3×33.2kJ/mol + (-285.8kJ/mol) - (2×-207.0kJ/mol + 91.3kJ/mol)}
ΔH°rxn = 136.5kJ/mol
And S°:
S°rxn = 3×S°NO2 + S°H2O - (2×S°HNO3 + S°NO)
ΔH°rxn = 3×0.2401kJ/molK + (0.0700kJ/molK) - (2×0.146kJ/molK + 0.2108kJ/molK)
ΔH°rxn = 0.2875kJ/molK
And replacing in (1) at 298K:
ΔG°rxn = 136.5kJ/mol - 298K×0.2875kJ/molK
<em>ΔG°rxn = +50.8 kJ/mol</em>
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