Worksheet: Balancing Equations
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The structural formula of <span>s-allylcysteine is shown in the picture (top figure). To create its Lewis structure, draw all its bonds between elements. Each single bond contains two electrons. There is an octet rule that must be obeyed by most elements. Each element should be surrounded with 8 electrons. The hydrogen is exempted of this rule. So, there are 4 lone pairs for the S atom, 1 lone pair for the N atom, and 2 lone pairs each for the 2 O atoms.</span>
Here we have to get the of the reaction at 520 K temperature.
The of the reaction is 1.705 atm
We know the relation between and
is
, where
= The equilibrium constant of the reaction in terms of partial pressure,
= The equilibrium constant of the reaction in terms of concentration and N = number of moles of gaseous products - Number of moles of gaseous reactants.
Now in this reaction, PCl₃ + Cl₂ ⇄ PCl₅
Thus number of moles of gaseous product is 1, and number of moles of gaseous reactants are 2. Thus N = |1 - 2| = 1 mole
The given value of is 4.0×10⁻²
The molar gas constant, R = 0.082 L. Atm. mol⁻¹. K⁻¹ and temperature, T = 520 K.
On plugging the values in the equation we get,
Or, = 1.705 atm
Thus, the of the reaction is 1.705 atm