Answer:
ΔG° = -5.4 kJ/mol
ΔG = 873.2 J/mol = 0.873 kJ /mol
Explanation:
Step 1: Data given
ΔG (NO2) = 51.84 kJ/mol
ΔG (N2O4) = 98.28 kJ/mol
Step 2:
ΔG = ΔG° + RT ln Q
⇒with Q = the reaction quatient
⇒with T = the temperature = 298 K
⇒with R = 8.314 J / mol*K
⇒with ΔG° = ΔG° (N2O4) - 2*ΔG°(NO2
)
⇒ ΔG° = 98.28 kJ/mol - 2* 51.84 kJ/mol
⇒ ΔG° = -5.4 kJ/mol
Part B
ΔG = ΔG° =RT ln Q
⇒with G° = -5.4 kj/mol = -5400 j/mol
⇒
with R = 8.314 J/K*mol
⇒with T = 298 K
⇒with Q = p(N2O4)/ [ p(NO2) ]² = 1.63/0.36² = 12.577
ΔG = -5400 + 8.314 * 298 * ln(12.577)
ΔG = -5400 + 8.314 * 298 * 2.532
ΔG = 873.2 J/mol = 0.873 kJ/mol
Answer : The concentration of A after 80 min is, 0.100 M
Explanation :
Half-life = 20 min
First we have to calculate the rate constant, we use the formula :
Expression for rate law for first order kinetics is given by:
where,
k = rate constant =
t = time passed by the sample = 80 min
a = initial amount of the reactant = 1.6 M
a - x = amount left after decay process = ?
Now put all the given values in above equation, we get
Therefore, the concentration of A after 80 min is, 0.100 M
Answer:
can oxygen exist as a liquid and solid
1- evaporation 2- transpiration 3-condensation 4- precipitation