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3 years ago

Organize the following list of elements from highest to lowest Ionization Energy:

1 answer:

7 0

Answer: The list of elements from highest to lowest Ionization Energy is Nitrogen > Phosphorus > Arsenic > Antimony > Bismuth.

Explanation:

The amount of energy required to remove the most loosely bound electron from an isolated gaseous atom or ion is called ionization energy.

Element with a half-filled orbital requires much more energy to remove an electron. This is because element with a half-filled electronic configuration is the most stable in nature.

More stable or tightly electrons are bound to the nucleus of an atom more will be its ionization energy. This also means that smaller is the atom higher will be its ionization energy.

When we move from top to bottom in a group the size of atom increases and the attraction between nucleus of atom and its valence electrons decreases. Hence, less will be the ionization energy.

Therefore, ionization energy decreases on moving down a group.

So, the given elements Phosphorus, Bismuth, Arsenic, Antimony, Nitrogen are all group 15 elements. Hence, decreasing order of their ionization energy is as follows.

Nitrogen > Phosphorus > Arsenic > Antimony > Bismuth

Thus, we can conclude that the list of elements from highest to lowest Ionization Energy is Nitrogen > Phosphorus > Arsenic > Antimony > Bismuth.

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The answers for the following sums is given below.

1. $Pd_{2}H_{2}$

2. $C_{2} H_{6}$

3. $C_{2} H_{2} O_{2} Cl_{2}$

4. $C_{3}Cl_{3} N_{3}$

5. $Tl_{2 } C_{4} H_{4}O_{6}$

6. $C_{8}H_{8}$

7. $N_{2}O_{5}$

8. $P_{4}O_{6}$

9. $C_{4}H_{8} O_{2}$

Explanation:

1.Given:

Molar mass=216.8g

Molecular formula=Pd $H_{2}$

we know;

Molecular formula=n(Empirical formula)

molecular weight of palladium(Pd)=106.4u

molecular weight of hydrogen(H)=1u

Molar mass of Pd $H_{2}$ :

Pd=106.4×1=106.4u

H=1×2=2

molar mass of Pd $H_{2}$ =106.4+2=108.4

n= $\frac{216.8}{106.4}$

n=2

Molecular formula=2(Pd $H_{2}$ )

Molecular formula= $Pd_{2}H_{2}$

Therefore the molecular formula of the compound is $Pd_{2}H_{2}$

2. Given:

Molar mass=30.0g

Molecular formula= $CH_{3}$

we know;

Molecular formula = n (Empirical formula)

molecular weight of Carbon(C)=12.01u

molecular weight of hydrogen(H)=1u

Molar mass of $CH_{3}$ :

C=12.01 × 1 = 12.01u

H=1 × 3 = 3u

molar mass of $CH_{3}$ =12.01 + 3 =15.01u

n= $\frac{30.0}{15.01}$

n=2

Molecular formula=2( $CH_{3}$ )

Molecular formula= $C_{2} H_{6}$

Therefore the molecular formula of the compound is $C_{2} H_{6}$

3. Given:

Molar mass=129g

Molecular formula=CHOCl

we know;

Molecular formula = n (Empirical formula)

molecular weight of Carbon(C)=12.01u

molecular weight of hydrogen(H)=1u

molecular weight of oxygen(O)=16.00u

molecular weight of chlorie(Cl)=35.5u

Molar mass of CHOCl:

C=12.01 × 1 = 12.01u

H=1 × 1 = 1u

O=16.00×1=16.00u

Cl=35.5×1=35.5u

molar mass of CHOCl=12.01+1+16.00+35.5=64.5u

n= $\frac{129}{64.5}$

n=2

Molecular formula=2(CHOCl)

Molecular formula= $C_{2} H_{2} O_{2} Cl_{2}$

Therefore the molecular formula of the compound is $C_{2} H_{2} O_{2} Cl_{2}$

5. Given:

Molar mass=577g

Molecular formula= $TlC_{2} H_{2}O_{3}$

we know;

Molecular formula = n (Empirical formula)

molecular weight of Carbon(C)=12.01u

molecular weight of Thallium(Tl)=204.3u

molecular weight of hydrogen(H)=1u

molecular weight of oxygen(O)=16.00u

Molar mass of $TlC_{2} H_{2}O_{3}$ :

C=12.01 × 2= 24.02u

Tl=204.3×1=204.3u

H=1×2=2u

O=16.00×3=48.00

molar mass of $TlC_{2} H_{2}O_{3}$ =204.3+24.02+1+48.00=278.32u

n= $\frac{577}{278.32}$

n=2

Molecular formula=2 ( $TlC_{2} H_{2}O_{3}$ )

Molecular formula= $Tl_{2 } C_{4} H_{4}O_{6}$

Therefore the molecular formula of the compound is $Tl_{2 } C_{4} H_{4}O_{6}$

4. Molar mass=184.5g

Molecular formula=CClN

we know;

Molecular formula = n (Empirical formula)

molecular weight of Carbon(C)=12.01u

molecular weight of Nitrogen(N)=14u

molecular weight of chlorine(Cl)=35.5u

Molar mass of CClN:

C=12.01 × 1 = 12.01u

N=1×14=14U

Cl=35.5×1=35.5u

molar mass of CClN=12.01+14+35.5=61.5u

n= $\frac{184.5}{61.5}$

n=3

Molecular formula=3 (CClN)

Molecular formula= $C_{3}Cl_{3} N_{3}$

Therefore the molecular formula of the compound is $C_{3}Cl_{3} N_{3}$

6. For the table refer the attached file.

Simplest ratio of elements:

Carbon=8

Hydrogen=8

Empirical formula= $C_{8}H_{8}$

Molecular formula = $C_{8}H_{8}$

Molar mass of $C_{8}H_{8}$ :

molecular weight of carbon=12.04u

molecular weight of hydrogen=1u

C=8×12.01=96.08u

H=1×8=8u

molar mass of $C_{8}H_{8}$ =96.08+8=104.08u

n=104.08÷78.0

n=1

Molecular formula = n(Empirical formula)

Molecular formula = 1( $C_{8}H_{8}$ )

Molecular formula = $C_{8}H_{8}$

Therefore the molecular formula of a compound is $C_{8}H_{8}$

7. Given:

mass of oxide of nitrogen=108g

mass of nitrogen=4.02g

mass of oxygen=11.48g

moles of nitrogen= $\frac{4.04}{14.01}$ = 0.289 moles

moles of oxygen= $\frac{11.46}{15.999}$ =0.716 moles

We divide through by the lowest molar quantity to give an empirical formula of $N_{2} O{5}$ .

Now the molecular formula is multiple of the empirical formula.

So,

108 = n × (2×14.01 + 5×15.999)

Clearly,n=1, and the molecular formula is $N_{2}O_{5}$ .

8.For the table refer the attached file.

Simplest ratio of elements:

Phosphorus=2

Oxygen=3

We know;

Empirical formula= $P_{2} O_{3}$

molecular formula= 2(Empirical formula)

Molecular formula =2( $P_{2} O_{3}$ )

Molecular formula = $P_{4}O_{6}$

Therefore the molecular formula of the compound is $P_{4}O_{6}$

9. For the table refer the attached file.

Simplest ratio of elements:

Carbon=2

Hydrogen=9

Oxygen=2

We know;

Empirical formula = $C_{2} H_{4} O$

Molecular formula = 2(Empirical formula)

Molecular formula =2( $C_{2} H_{4} O$ )

Molecular formula = $C_{4}H_{8} O_{2}$

Therefore the molecular formula of the compound is $C_{4}H_{8} O_{2}$

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