Answer:
Mass of Rb-87 is 86.913 amu.
Explanation:
Given data:
Average mass of rubidium = 85.4678 amu
Mass of Rb-85 = 84.9117
Ratio of 85Rb/87Rb in natural rubidium = 2.591
Mass of Rb = ?
Solution:
The ration of both isotope is 2.591 to 1. Which means that for 2.591 atoms of Rb-85 there is one Rb-87.
For 100% naturally occurring Rb = 2.591 + 1 = 3.591
% abundance of Rb-85 = 2.591/ 3.591 = 0.722
% abundance of Rb-87 = 1 - 0.722= 0.278
84.9117 × 0.722 + X × 0.278 = 85.4678
61.306 + X × 0.278 = 85.4678
X × 0.278 = 85.4678 - 61.306
X × 0.278 = 24.1618
X = 24.1618 / 0.278
X = 86.913 amu
Nonmetals don’t have enough electronegativity to transfer electrons so the electrons are shared between them
Answer:
pKa of the histidine = 9.67
Explanation:
The relation between standard Gibbs energy and equilibrium constant is shown below as:
R is Gas constant having value = 0.008314 kJ / K mol
Given temperature, T = 293 K
Given,
So, Applying in the equation as:-
Thus,
![\frac{[His]}{[His+]}=e^{\frac{15}{-0.008314\times 293}](https://tex.z-dn.net/?f=%5Cfrac%7B%5BHis%5D%7D%7B%5BHis%2B%5D%7D%3De%5E%7B%5Cfrac%7B15%7D%7B-0.008314%5Ctimes%20293%7D)
![\frac{[His]}{[His+]}=0.00211](https://tex.z-dn.net/?f=%5Cfrac%7B%5BHis%5D%7D%7B%5BHis%2B%5D%7D%3D0.00211)
Also, considering:-
![pH=pKa+log\frac{[His]}{[His+]}](https://tex.z-dn.net/?f=pH%3DpKa%2Blog%5Cfrac%7B%5BHis%5D%7D%7B%5BHis%2B%5D%7D)
Given that:- pH = 7.0
So, 
<u>pKa of the histidine = 9.67</u>
I'm not positive, but I believe it would be one near the Rocky Mountains.