1) Chemical equation
Na2 SiO3 (s) + 8 HF (aq) ---> H2 Si F6 (aq) + 2 Na F (aq) + 3H2O (l)
It is balanced
2) Molar ratios
1 mol Na2 SiO3 : 8 mol HF.
3) Proportion
0.340 mol Na2 SiO3 * 8 mol HF / 1mol Na2SiO3 = 2.72 mol HF.
Answer: 2.72 mol HF
the calculated value is Ea is 18.2 KJ and A is 12.27.
According to the exponential part in the Arrhenius equation, a reaction's rate constant rises exponentially as the activation energy falls. The rate also grows exponentially because the rate of a reaction is precisely proportional to its rate constant.
At 500K, K=0.02s−1
At 700K, k=0.07s −1
The Arrhenius equation can be used to calculate Ea and A.
RT=k=Ae Ea
lnk=lnA+(RT−Ea)
At 500 K,
ln0.02=lnA+500R−Ea
500R Ea (1) At 700K lnA=ln (0.02) + 500R
lnA = ln (0.07) + 700REa (2)
Adding (1) to (2)
700REa100R1[5Ea-7Ea] = 0.02) +500REa=0.07) +700REa.
=ln [0.02/0 .07]
Ea= 2/35×100×8.314×1.2528
Ea =18227.6J
Ea =18.2KJ
Changing the value of E an in (1),
lnA=0.02) + 500×8.314/18227.6
= (−3.9120) +4.3848
lnA=0.4728
logA=1.0889
A=antilog (1.0889)
A=12.27
Consequently, Ea is 18.2 KJ and A is 12.27.
Learn more about Arrhenius equation here-
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