What are the missing coefficients for the skeleton equation below? Cr(s) + Fe(NO3)2(aq) → Fe(s) + Cr(NO3)3(aq)

Express the van der Waals equation of state as a virial expansion in powers of 1/Vm and obtain expressions for B and C in terms

nirvana33 [79]

Answer:

$PV_{m} = RT[1 + (b-\frac{a}{RT})\frac{1}{V_{m} } + \frac{b^{2} }{V^{2} _{m} } + ...]$

B = b -a/RT

C = b^2

a = 1.263 atm*L^2/mol^2

b = 0.03464 L/mol

Explanation:

In the given question, we need to express the van der Waals equation of state as a virial expansion in powers of 1/Vm and obtain expressions for B and C in terms of the parameters a and b. Therefore:

Using the van deer Waals equation of state:

$P = \frac{RT}{V_{m}-b } - \frac{a}{V_{m} ^{2} }$

With further simplification, we have:

$P = RT[\frac{1}{V_{m}-b } - \frac{a}{RTV_{m} ^{2} }]$

Then, we have:

$P = \frac{RT}{V_{m} } [\frac{1}{1-\frac{b}{V_{m} } } - \frac{a}{RTV_{m} }]$

Therefore,

$PV_{m} = RT[(1-\frac{b}{V_{m} }) ^{-1} - \frac{a}{RTV_{m} }]$

Using the expansion:

$(1-x)^{-1} = 1 + x + x^{2} + ....$

Therefore,

$PV_{m} = RT[1+\frac{b}{V_{m} }+\frac{b^{2} }{V_{m} ^{2} } + ... -\frac{a}{RTV_{m} }]$

Thus:

$PV_{m} = RT[1 + (b-\frac{a}{RT})\frac{1}{V_{m} } + \frac{b^{2} }{V^{2} _{m} } + ...]$ equation (1)

Using the virial equation of state:

$P = RT[\frac{1}{V_{m} }+ \frac{B}{V_{m} ^{2}}+\frac{C}{V_{m} ^{3} }+ ...]$

Thus:

$PV_{m} = RT[1+ \frac{B}{V_{m} }+ \frac{C}{V_{m} ^{2} } + ...]$ equation (2)

Comparing equations (1) and (2), we have:

B = b -a/RT

C = b^2

Using the measurements on argon gave B = −21.7 cm3 mol−1 and C = 1200 cm6 mol−2 for the virial coefficients at 273 K.

$b = \sqrt{C} = \sqrt{1200} = 34.64[tex]cm^{3}/mol$ [/tex] = 0.03464 L/mol

a = (b-B)*RT = (34.64+21.7)*(1L/1000cm^3)*(0.0821)*(273) = 1.263 atm*L^2/mol^2

3 0

2 years ago

In which shell are the valence electrons of the elements in Period 2 found?

defon

B 2
is which shell are the valence electrons of the elements in period 2 found

8 0

2 years ago

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If you initially have a volume of 4 L and a temperature of 300K. Then you decreased the volume to 2 L, what is the new temperatu

ASHA 777 [7]

Answer:

T₂ = 150 K

Explanation:

Given data:

Initial volume = 4 L

Initial temperature = 300 K

Final volume = 2 L

Final temperature = ?

Solution:

The given problem will be solve through the Charles Law.

According to this law, The volume of given amount of a gas is directly proportional to its temperature at constant number of moles and pressure.

Mathematical expression:

V₁/T₁ = V₂/T₂

V₁ = Initial volume

T₁ = Initial temperature

V₂ = Final volume

T₂ = Final temperature

Now we will put the values in formula.

V₁/T₁ = V₂/T₂

T₂ = T₁V₂/V₁

T₂ = 300 K × 2L / 4 L

T₂ = 600 L.K / 4 L

T₂ = 150 K

3 0

2 years ago

Number of protons for oxygen 16

DanielleElmas [232]

8 protons in oxygen bc it has an atomic number of 8

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3 years ago

Which of the following statements regarding energy changes during a reaction are true?. 1) If the heat of reaction, ΔH, is negat

sergejj [24]

2.<span>Two or more atoms must collide, with proper orientation, with energy greater than or equal to the activation energy for a reaction to occur</span>

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2 years ago

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