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oee [108]
3 years ago
8

The accepted value for the density of a certain material is 3.427 g/ml. Ally 10 points

Chemistry
1 answer:
vivado [14]3 years ago
7 0

Answer:

5.04%

Explanation:

The accepted value of density = 3.427 g/ml

The calculated value of density = 3.600 g/ml

We need to find Ally's percentage error on  her density. The error in any value is given by :

\%=\dfrac{\text{calculated-accepted}}{\text{accepted}}\times 100\\\\=\dfrac{3.427 -3.600 }{3.427 }\times 100\\\\=5.04\%

So, the required error is 5.04%.

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Explanation:

All three lighter boron trihalides, BX3 (X = F, Cl, Br), form stable adducts with common Lewis bases. Their relative Lewis acidities can be evaluated in terms of the relative exothermicities of the adduct-forming reaction. Such measurements have revealed the following sequence for the Lewis acidity: BF3 < BCl3 < BBr3 (in other words, BBr3 is the strongest Lewis acid).

This trend is commonly attributed to the degree of π-bonding in the planar boron trihalide that would be lost upon pyramidalization (the conversion of the trigonal planar geometry to a tetrahedral one) of the BX3 molecule, which follows this trend: BF3 > BCl3 > BBr3 (that is, BBr3 is the most easily pyramidalized). The criteria for evaluating the relative strength of π-bonding are not clear, however. One suggestion is that the F atom is small compared to the larger Cl and Br atoms, and the lone pair electron in the 2pzorbital of F is readily and easily donated, and overlaps with the empty 2pz orbital of boron. As a result, the [latex]\pi[/latex] donation of F is greater than that of Cl or Br. In an alternative explanation, the low Lewis acidity for BF3 is attributed to the relative weakness of the bond in the adducts F3B-L.

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For example an ionic bonding scenario might play out between a group one metal and a group seven halogen. While group one metals have one electron hindering their stability, group seven halogens need that one electron that could make them achieve this stability. It is this that causes them to come together in a way where the electron is transferred completely from the valence shell of the group 1 atom and accepted into the valence shell of the group 7 halogen.

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