<u>Answer:</u> The pH of resulting solution is 8.7
<u>Explanation:</u>
To calculate the number of moles for given molarity, we use the equation:
Molarity of TRIS acid solution = 0.1 M
Volume of solution = 50 mL
Putting values in above equation, we get:
Molarity of TRIS base solution = 0.2 M
Volume of solution = 60 mL
Putting values in above equation, we get:
Volume of solution = 50 + 60 = 110 mL = 0.11 L (Conversion factor: 1 L = 1000 mL)
- To calculate the pH of acidic buffer, we use the equation given by Henderson Hasselbalch:
![pH=pK_a+\log(\frac{[salt]}{[acid]})](https://tex.z-dn.net/?f=pH%3DpK_a%2B%5Clog%28%5Cfrac%7B%5Bsalt%5D%7D%7B%5Bacid%5D%7D%29)
![pH=pK_a+\log(\frac{[\text{TRIS base}]}{[\text{TRIS acid}]})](https://tex.z-dn.net/?f=pH%3DpK_a%2B%5Clog%28%5Cfrac%7B%5B%5Ctext%7BTRIS%20base%7D%5D%7D%7B%5B%5Ctext%7BTRIS%20acid%7D%5D%7D%29)
We are given:
= negative logarithm of acid dissociation constant of TRIS acid = 8.3
![[\text{TRIS acid}]=\frac{0.005}{0.11}](https://tex.z-dn.net/?f=%5B%5Ctext%7BTRIS%20acid%7D%5D%3D%5Cfrac%7B0.005%7D%7B0.11%7D)
![[\text{TRIS base}]=\frac{0.012}{0.11}](https://tex.z-dn.net/?f=%5B%5Ctext%7BTRIS%20base%7D%5D%3D%5Cfrac%7B0.012%7D%7B0.11%7D)
pH = ?
Putting values in above equation, we get:
Hence, the pH of resulting solution is 8.7
Answer:
9.63 L of NO
Explanation:
We'll begin by calculating the number of mole in 50.0 g of NH₄ClO₄. This can be obtained as follow:
Mass of NH₄ClO₄ = 50 g
Molar mass of NH₄ClO₄ = 14 + (4×1) + 35.5 + (16×4)
= 14 + 4 + 35.5 + 64
= 117.5 g/mol
Mole of NH₄ClO₄ =?
Mole = mass /molar mass
Mole of NH₄ClO₄ = 50/117.5
Mole of NH₄ClO₄ = 0.43 mole
Next, we shall determine the number of mole of NO produced by the reaction of 50 g (i.e 0.43 mole) of NH₄ClO₄. This can be obtained as follow:
3Al + 3NH₄ClO₄ –> Al₂O₃ + AlCl₃ + 3NO + 6H₂O
From the balanced equation above,
3 moles of NH₄ClO₄ reacted to produce 3 moles of NO.
Therefore, 0.43 mole of NH₄ClO₄ will also react to produce 0.43 mole of NO.
Finally, we shall determine the volume occupied by 0.43 mole of NO. This can be obtained as follow:
1 mole of NO = 22.4 L
Therefore,
0.43 mole of NO = 0.43 × 22.4
0.43 mole of NO = 9.63 L
Thus, 9.63 L of NO were obtained from the reaction.
