Answer:
(a) Benzene = 0.26; toluene = 0.74
(b) Benzene = 0.55
Explanation:
1. Calculate the composition of the solution
For convenience, let’s call benzene Component 1 and toluene Component 2.
According to Raoult’s Law,
where
p₁ and p₂ are the vapour pressures of the components above the solution
χ₁ and χ₂ are the mole fractions of the components
p₁° and p₂° are the vapour pressures of the pure components.
Note that
χ₁ + χ₂ = 1
So,
χ₁ = 0.26 and χ₂ = 0.74
2. Calculate the mole fraction of benzene in the vapour
In the liquid,
p₁ = χ₁p₁° = 0.26 × 75 mm = 20 mm
∴ In the vapour
Note that the vapour composition diagram below has toluene along the horizontal axis. The purple line is the vapour pressure curve for the vapour. Since χ₂ has dropped to 0.45, χ₁ has increased to 0.55.
Answer: The hydroboration of an alkene occurs in TWO CONCERTED STEP which places the boron of the borane on the LESS SUBSTITUTED carbon of the double bond. The oxidizing agent then acts as a nucleophile, attacking the electrophilic BORON and resulting in the placement of a hydroxyl group on the attached carbon. Thus, the major product of the hydroboration oxidation reaction DOES NOT follow Markovnikov's rule.
Explanation:
Hydroboration is defined as the process which allows boron to attain the octet structure. This involves a two steps pathway which leads to the production of alcohol.
--> The first step: this involves the initiation of the addittion of borane to the alkene and this proceeds as a concerted reaction because bond breaking and bond formation occurs at the same time.
--> The second step: this involves the addition of boron which DOES NOT follow Markovnikov's rule( that is, Anti Markovnikov addition of Boron). This is so because the boron adds to the less substituted carbon of the alkene, which then places the hydrogen on the more substituted carbon.
Note: The Markovnikov rule in organic chemistry states that in alkene addition reactions, the electron-rich component of the reagent adds to the carbon atom with fewer hydrogen atoms bonded to it, while the electron-deficient component adds to the carbon atom with more hydrogen atoms bonded to it.
<span>the process or action by which one thing absorbs or is absorbed by another.</span>
Northern atlantic and northern pacific oceans
<span>chemicals reacting are written on the left, what is formed is written on the right after the = sign
eg Copper + oxygen = copper oxide.
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