It is unique because we can drink from it .
Answer:
2
Explanation:
Half-life
Concentration
![{[A]_0}_A=1.2\ \text{M}](https://tex.z-dn.net/?f=%7B%5BA%5D_0%7D_A%3D1.2%5C%20%5Ctext%7BM%7D)
![{[A]_0}_B=0.6\ \text{M}](https://tex.z-dn.net/?f=%7B%5BA%5D_0%7D_B%3D0.6%5C%20%5Ctext%7BM%7D)
We have the relation
![t_{1/2}\propto \dfrac{1}{[A]_0^{n-1}}](https://tex.z-dn.net/?f=t_%7B1%2F2%7D%5Cpropto%20%5Cdfrac%7B1%7D%7B%5BA%5D_0%5E%7Bn-1%7D%7D)
So
![\dfrac{{t_{1/2}}_A}{{t_{1/2}}_B}=\left(\dfrac{{[A]_0}_B}{{[A]_0}_A}\right)^{n-1}\\\Rightarrow \dfrac{2}{4}=\left(\dfrac{0.6}{1.2}\right)^{n-1}\\\Rightarrow \dfrac{1}{2}=\left(\dfrac{1}{2}\right)^{n-1}](https://tex.z-dn.net/?f=%5Cdfrac%7B%7Bt_%7B1%2F2%7D%7D_A%7D%7B%7Bt_%7B1%2F2%7D%7D_B%7D%3D%5Cleft%28%5Cdfrac%7B%7B%5BA%5D_0%7D_B%7D%7B%7B%5BA%5D_0%7D_A%7D%5Cright%29%5E%7Bn-1%7D%5C%5C%5CRightarrow%20%5Cdfrac%7B2%7D%7B4%7D%3D%5Cleft%28%5Cdfrac%7B0.6%7D%7B1.2%7D%5Cright%29%5E%7Bn-1%7D%5C%5C%5CRightarrow%20%5Cdfrac%7B1%7D%7B2%7D%3D%5Cleft%28%5Cdfrac%7B1%7D%7B2%7D%5Cright%29%5E%7Bn-1%7D)
Comparing the exponents we get
The order of the reaction is 2.
![t_{1/2}=\dfrac{1}{k[A]_0^{n-1}}\\\Rightarrow k=\dfrac{1}{t_{1/2}[A]_0^{n-1}}\\\Rightarrow k=\dfrac{1}{2\times 1.2^{2-1}}\\\Rightarrow k=0.4167\ \text{M}^{-1}\text{min}^{-1}](https://tex.z-dn.net/?f=t_%7B1%2F2%7D%3D%5Cdfrac%7B1%7D%7Bk%5BA%5D_0%5E%7Bn-1%7D%7D%5C%5C%5CRightarrow%20k%3D%5Cdfrac%7B1%7D%7Bt_%7B1%2F2%7D%5BA%5D_0%5E%7Bn-1%7D%7D%5C%5C%5CRightarrow%20k%3D%5Cdfrac%7B1%7D%7B2%5Ctimes%201.2%5E%7B2-1%7D%7D%5C%5C%5CRightarrow%20k%3D0.4167%5C%20%5Ctext%7BM%7D%5E%7B-1%7D%5Ctext%7Bmin%7D%5E%7B-1%7D)
The rate constant is
First, we need to get n1 (no.of moles of water ): when
mass of water = 0.0203 g and the volume = 1.39 L
∴ n1 = mass / molar mass of water
= 0.0203g / 18 g/mol
= 0.00113 moles
then we need to get n2 (no of moles of water) after the mass has changed:
when the mass of water = 0.146 g
n2 = mass / molar mass
= 0.146g / 18 g/ mol
= 0.008 moles
so by using the ideal gas formula and when the volume is not changed:
So, P1/n1 = P2/n2
when we have P1 = 1.02 atm
and n1= 0.00113 moles
and n2 = 0.008 moles
so we solve for P2 and get the pressure
∴P2 = P1*n2 / n1
=1.02 atm *0.008 moles / 0.00113 moles
= 7.22 atm
∴the new pressure will be 7.22 atm
