Answer:
It means the chemical entity is a radical
Explanation:
When we talk of unsaturation, we are referring to the number of pi-bonds in a chemical entity. The alkane, alkene and alkyne organic family are used to as common examples to explain the term unsaturation.
While alkynes have 3 bonds, it must be understood that they have 2 pi bonds only and as such their degree of saturation is two.
In the case of an alkene, there is only one single pi bond and as such the degree of unsaturation is 1.
Now in this case, we have a fractional 0.5 degree of unsaturation alongside the 3 to make a total of 3.5. So what’s the issue here?
The fractional part shows that the chemical entity we are dealing with here is a radical. While the integer 3 shows that there are 3 pi-bonds, the half pi bond remaining tells us that there is a missing electron on one of the atoms involved in the chemical bonding and as such, the 1/2 extra degree of unsaturation tends to tell us this.
Kindly recall that a radical is a chemical entity within which we have at the least an unpaired electron.
Answer:
The over all charge on atom will be +2.
Explanation:
An atom consist of electron, protons and neutrons. Protons and neutrons are present with in nucleus while the electrons are present out side the nucleus.
All these three subatomic particles construct an atom. A neutral atom have equal number of proton and electron. In other words we can say that negative and positive charges are equal in magnitude and cancel the each other. For example if neutral atom has 6 protons than it must have 6 electrons. The sum of neutrons and protons is the mass number of an atom while the number of protons are number of electrons is the atomic number of an atom.
For example
X is the element having 12 protons 10 electrons and 14 neutrons.
The number of protons and electrons are not equal which means two electrons are lose by the given atom and it is present in the form of cation.
The over all charge on atom will be +2.
Answer:
The correct answer is 160.37 KJ/mol.
Explanation:
To find the activation energy in the given case, there is a need to use the Arrhenius equation, which is,
k = Ae^-Ea/RT
k1 = Ae^-Ea/RT1 and k2 = Ae^-Ea/RT2
k2/k1 = e^-Ea/R (1/T2-1/T1)
ln(k2/k1) = Ea/R (1/T1-1/T2)
The values of rate constant k1 and k2 are 3.61 * 10^-15 s^-1 and 8.66 * 10^-7 s^-1.
The temperatures T1 and T2 are 298 K and 425 K respectively.
Now by filling the values we get:
ln (8.66*10^-7/3.61*10^-15) = Ea/R (1/298-1/425)
19.29 = Ea/R * 0.001
Ea = 160.37 KJ/mol