The 1st law of thermodynamics doesn't specify that matter can be created nor destroyed, but that the total amount of energy in a closed system cannot be created nor destroyed though it can be changed from one form to another.
Answer:

Explanation:
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In this case, according to the Avogadro's number, it is possible to compute the atoms of Kr in 2.00 moles as shown below:

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<u>Answer:</u> The expression for equilibrium constant is ![K_{eq}=\frac{[HOCl]^2}{[H_2O][Cl_2]^2}](https://tex.z-dn.net/?f=K_%7Beq%7D%3D%5Cfrac%7B%5BHOCl%5D%5E2%7D%7B%5BH_2O%5D%5BCl_2%5D%5E2%7D)
<u>Explanation:</u>
Equilibrium constant is defined as the ratio of concentration of products to the concentration of reactants each raised to the power their stoichiometric ratios. It is expressed as 
For the general chemical equation:

The expression for
is given as:
![K_c=\frac{[C]^c[D]^d}{[A]^a[B]^b}](https://tex.z-dn.net/?f=K_c%3D%5Cfrac%7B%5BC%5D%5Ec%5BD%5D%5Ed%7D%7B%5BA%5D%5Ea%5BB%5D%5Eb%7D)
For the given chemical reaction:

The expression for
is given as:
![K_{eq}=\frac{[HOCl]^2[HgO.HgCl_2]}{[HgO]^2[H_2O][Cl_2]^2}](https://tex.z-dn.net/?f=K_%7Beq%7D%3D%5Cfrac%7B%5BHOCl%5D%5E2%5BHgO.HgCl_2%5D%7D%7B%5BHgO%5D%5E2%5BH_2O%5D%5BCl_2%5D%5E2%7D)
The concentration of solid is taken to be 0.
So, the expression for
is given as:
![K_{eq}=\frac{[HOCl]^2}{[H_2O][Cl_2]^2}](https://tex.z-dn.net/?f=K_%7Beq%7D%3D%5Cfrac%7B%5BHOCl%5D%5E2%7D%7B%5BH_2O%5D%5BCl_2%5D%5E2%7D)