Answer : The fuel value and the fuel density of pentane is, 49.09 kJ/g and
respectively.
Explanation :
Fuel value : It is defined as the amount of energy released from the combustion of hydrocarbon fuels. The fuel value always in positive and in kilojoule per gram (kJ/g).
As we are given that:

Fuel value = 
Molar mass of pentane = 72 g/mol
Fuel value = 
Fuel value = 49.09 kJ/g
Now we have to calculate the fuel density of pentane.
Fuel density = Fuel value × Density
Fuel density = (49.09 kJ/g) × (0.626g/mL)
Fuel density = 30.73 kJ/mL = 
Thus, the fuel density of pentane is 
The pressure would increase. When the temperature change form cold to hot, the gas will find ways to escape from containment. Thus, if it cannot escape that pressure will keep on increasing as the temperature rises.