That would be the NOBLE GASES (Helium, Neon, Argon, Krypton, Xenon, Radon). Because these elements have a filled outer shell (thus giving them the full octet that other elements crave), they are stable elements under normal circumstances and as such resist chemical combination.
Plz note that under special conditions, noble gases such as Xenon and Radon can form compounds (Xenon Fluoride and Oxide; Radon Fluoride)
Answer : The heat energy needed would be, 6486.5125 J
Explanation :
To calculate the change in temperature, we use the equation:

where,
q = heat needed = ?
m = mass of aluminum = 223 g
c = specific heat capacity of aluminum = 
= change in temperature
= initial temperature = 
= final temperature = 
Putting values in above equation, we get:


Therefore, the heat energy needed would be, 6486.5125 J
The known constant of water is that it freezes at 0 degrees Celsius and boils at 100 degrees Celsius. it can be determined that because of the solute added the water becomes a compound meaning it no longer has the constants of pure water hence the difference in freezing point