Answer:
MIXTURE , ELEMENT AND SUBSTANCE
Answer: The age of the tool is 15539 years
Explanation:
Expression for rate law for first order kinetics is given by:
where,
k = rate constant
t = age of sample
a = let initial amount of the reactant = 100
a - x = amount left after decay process =
a) for completion of half life:
Half life is the amount of time taken by a radioactive material to decay to half of its original value.

b) for 15.5 % of original amount

Thus age of the tool is 15539 years
calculate moles of both reagents given and the moles of FeS that each of them would form if they were in excess
moles = mass / molar mass
moles Fe = 7.62 g / 55.85 g/mol
= 0.1364 moles
1 mole Fe produces 1 mole FeS
Therefore 7.62 g Fe can form 0.1364 moles FeS
moles S = 8.67 g / 32.07 g/mol
= 0.2703 moles S
1 mole S can from 1 moles FeS
So 8.67 g S can produce 0.2703 moles FeS
The limiting reagent is the one that produces the least product. So Fe is limiting.
The maximum amount of FeS possible is from complete reaction of all the limiting reagent.
We have already determined that the Fe can form up to 0.1364 moles of FeS, so this is max amount of FeS you can get.
Convert to mass
hope this helps :)