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drek231 [11]
3 years ago
13

What was important about the Hydrogen bright line emission spectrum?

Chemistry
1 answer:
Art [367]3 years ago
5 0

Answer:

The emission spectrum lines are the changes in the quantum energy levels of the single electron in the Hydrogen atom.

Explanation:

Electrons move around the hydrogen atom in electron waves patterns. These waves occur in distinct quantum energy levels.

The change from one quantum energy level to another energy level has a definite energy level change. There is a wave length associated with each change in energy levels. These wave lengths have a color associated with them.

Low energy level changes have long wave lengths associated with them giving red and orange colors.

High energy level changes have short wave lengths associated with them giving blue and violet colors.

Note each atom has a unique emission spectrum associated with the energy levels and electron structure of the atom. Helium was first discovered by looking at its emission spectrum as seen in the sun.

Explanation:

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The standard reduction potentials of the following half-reactions are given in Appendix E in the textbook:
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<u>Answer:</u>

<u>For 1:</u> The largest positive cell potential is of cell having 1st and 4th half reactions.

<u>For 2:</u> The standard electrode potential of the cell is 1.539 V

<u>For 3:</u> The smallest positive cell potential is of cell having 3rd and 4th half reactions. The standard electrode potential of the cell is 0.46 V

<u>Explanation:</u>

The substance having highest positive E^o potential will always get reduced and will undergo reduction reaction.

We are given:

Ag^++(aq.)+e^-\rightarrow Ag(s);E^o_{Ag^+/Ag}=0.799V\\\\Cu^{2+}+(aq.)+2e^-\rightarrow Cu(s);E^o_{Cu^{2+}/Cu}=0.337V\\\\Ni^{2+}(aq.)+2e^-\rightarrow Ni(s);E^o_{Ni^{2+}/Ni}=-0.28V\\\\Cr^{3+}(aq.)+3e^-\rightarrow Cr(s);E^o_{Cr^{3+}/Cr}=-0.74V

Substance getting oxidized always act as anode and the one getting reduced always act as cathode.

To calculate the E^o_{cell} of the reaction, we use the equation:

E^o_{cell}=E^o_{cathode}-E^o_{anode}

  • <u>Cell having 1st and 2nd half reactions:</u>

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E^o_{cell}=0.799-0.337=0.462V

  • <u>Cell having 1st and 3rd half reactions:</u>

Silver has higher electrode potential. So, this will undergo reduction reaction and act as anode. Nickel will undergo oxidation reaction and act as cathode.

E^o_{cell}=0.799-(-0.28)=1.079V

  • <u>Cell having 1st and 4th half reactions:</u>

Silver has higher electrode potential. So, this will undergo reduction reaction and act as anode. Chromium will undergo oxidation reaction and act as cathode.

E^o_{cell}=0.799-(-0.74)=1.539V

  • <u>Cell having 2nd and 3rd half reactions:</u>

Copper has higher electrode potential. So, this will undergo reduction reaction and act as anode. Nickel will undergo oxidation reaction and act as cathode.

E^o_{cell}=0.337-(-0.28)=0.617V

  • <u>Cell having 3rd and 4th half reactions:</u>

Nickel has higher electrode potential. So, this will undergo reduction reaction and act as anode. Chromium will undergo oxidation reaction and act as cathode.

E^o_{cell}=-0.28-(-0.74)=0.46V

Hence,

<u>For 1:</u> The largest positive cell potential is of cell having 1st and 4th half reactions.

<u>For 2:</u> The standard electrode potential of the cell is 1.539 V

<u>For 3:</u> The smallest positive cell potential is of cell having 3rd and 4th half reactions. The standard electrode potential of the cell is 0.46 V

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