The absorbance reported by the defective instrument was 0.3933.
Absorbance A = - log₁₀ T
Tm = transmittance measured by spectrophotometer
Tm = 0.44
Absorbance reported in this equipment = -log₁₀ (0.44) = 0.35654
True absorbance can be calculated by true transmittance, Tm = T+S(α-T)
S = fraction of stray light = 6%= 6/100 = 0.06
α= 1, ideal case
T = true transmittance of the sample
Tm = T+S(α-T)
now, T= Tm-S/ 1-S = 0.44-0.06/ 1-0.06 = 0.404233
therefore, actual reading measured is A = -log₁₀ T = -log₁₀ (0.404233)
i.e; 0.3933
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This is covalent network type of solid.
For example, silicon dioxide (SiO₂) is covalent network solid with covalent bonding.
Covalent network solid is a chemical compound (or element) in which the atoms are bonded by covalent bonds in a continuous network extending throughout the material.
Silicon(IV) oxide has continuous three-dimensional network of SiO₂ units and diamond has sp3 hybridization.
This solids do not have free electrons so they are good insulators.
They have strong covalent bonds, so they melt at extremely high temperature.
Other examples are quartz, diamond, and silicon carbide.
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Answer:
0.121 moles of aluminum metal are required to produce 4.04 L of hydrogen gas at 1.11 atm and 27 °C by reaction with HCl
Explanation:
This is the reaction:
2 Al(s) + 6 HCl(aq) → 2 AlCl₃ (aq) + 3 H₂(g)
To make 3 moles of H₂, we need 2 moles of Al.
By conditions given, we will find out how many moles of H₂ do we have.
Let's use the Ideal Gas Law
P. V = n . R . T
1.11 atm . 4.04L = n . 0.082 L.atm/mol.K . 300K
(1.11 atm . 4.04L) / (0.082 mol.K/L.atm . 300K) = n
0.182 mol = n
So the rule of three will be:
If 3 moles of H₂ came from 2 moles of Al
0.182 moles of H₂ will come from x
(0.182 .2) / 3 = 0.121 moles
An increase in the number of gas molecules in the same volume container increases pressure. A decrease in container volume increases gas pressure. An increase in temperature of a gas in a rigid container increases the pressure.
