Answer:
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Explanation:
A hydrocarbon with three or more consecutive (cumulative) double bonds is known as a cumulene. They are analogous to allenes, only exhibiting a more elongated chain. The basic molecule in this category is butatriene, which is also simply known as cumulene.
In the structure of a cumulene, there are 3 double bonds and 4 single bonds. The double bond comprises 1 sigma bond, and 1 pi bond and 4 hydrogen bond produces a sigma bond with carbon. Thus, the molecule of cumulene comprises 7 sigma bonds and 3 pi bonds.
Answer:
Aluminium was named after alum, which is called 'alumen' in Latin. This name was given by Humphry Davy, an English chemist, who, in 1808, discovered that aluminium could be produced by electrolytic reduction from alumina (aluminium oxide), but did not manage to prove the theory in practice.
Explanation:
Answer:
K = Ka/Kb
Explanation:
P(s) + (3/2) Cl₂(g) <-------> PCl₃(g) K = ?
P(s) + (5/2) Cl₂(g) <--------> PCl₅(g) Ka
PCl₃(g) + Cl₂(g) <---------> PCl₅(g) Kb
K = [PCl₃]/ ([P] [Cl₂]⁽³'²⁾)
Ka = [PCl₅]/ ([P] [Cl₂]⁽⁵'²⁾)
Kb = [PCl₅]/ ([PCl₃] [Cl₂])
Since [PCl₅] = [PCl₅]
From the Ka equation,
[PCl₅] = Ka ([P] [Cl₂]⁽⁵'²⁾)
From the Kb equation
[PCl₅] = Kb ([PCl₃] [Cl₂])
Equating them
Ka ([P] [Cl₂]⁽⁵'²⁾) = Kb ([PCl₃] [Cl₂])
(Ka/Kb) = ([PCl₃] [Cl₂]) / ([P] [Cl₂]⁽⁵'²⁾)
(Ka/Kb) = [PCl₃] / ([P] [Cl₂]⁽³'²⁾)
Comparing this with the equation for the overall equilibrium constant
K = Ka/Kb
