Your question, I guess, How do vapour and gases differ...
Answer:
1.) Vapour is the changed state of any liquid either due to boiling or evaporation
2.) Vapour are more energetic as they have absorbed the latent heat of vaporization whereas Gases are low in energy because they are already in gaseous form at room temperature.
3.) Vapour have boiling points above room temperature while gases have their boiling point below room temperature.
Since the mass of a single popcorn kernel is not given, lets us assume that it is 1 gram
Now:
1 mole of popcorn kernels contain
kernels
Since:
1 kernel weighs 1 gram
Then,
kernels would weigh
grams
Answer : The final concentration of
is, 2.9 M
Explanation :
Expression for rate law for first order kinetics is given by:

where,
k = rate constant = 
t = time passed by the sample = 3.5 min
a = initial concentration of the reactant = 3.0 M
a - x = concentration left after decay process = ?
Now put all the given values in above equation, we get


Thus, the final concentration of
is, 2.9 M