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In the redox conversion of Ni2+ to NiO4−, the oxidation number of Ni goes from (−2, 0, +2) to (−1, +1, +7, +9). Recall that the

inessss [21]

Oxidation number of an atom is the charge that atom would have if the compound is composed of ions. In neutral substances that contains atoms of one element the oxidation number of an atom is zero. Thus atoms in O2, Ni2, and aluminium all have oxidation number of zero.
In this case, Ni2, the oxidation number of Ni atom is zero,
for NiO4-, assuming oxidation number of Ni is x
(x ×1) + (-2 × 4) = -1
x = + 7
Therefore, the oxidation number goes from 0 to +7

7 0

3 years ago

An ideal gas (C}R), flowing at 4 kmol/h, expands isothermally at 475 Kfrom 100 to 50 kPa through a rigid device. If the power pr

Zina [86]

<u>Answer:</u> The rate of heat flow is 3.038 kW and the rate of lost work is 1.038 kW.

<u>Explanation:</u>

We are given:

$C_p=\frac{7}{2}R\\\\T=475K\\P_1=100kPa\\P_2=50kPa$

Rate of flow of ideal gas , n = 4 kmol/hr = $\frac{4\times 1000mol}{3600s}=1.11mol/s$ (Conversion factors used: 1 kmol = 1000 mol; 1 hr = 3600 s)

Power produced = 2000 W = 2 kW (Conversion factor: 1 kW = 1000 W)

We know that:

$\Delta U=0$ (For isothermal process)

So, by applying first law of thermodynamics:

$\Delta U=\Delta q-\Delta W$

$\Delta q=\Delta W$ .......(1)

Now, calculating the work done for isothermal process, we use the equation:

$\Delta W=nRT\ln (\frac{P_1}{P_2})$

where,

$\Delta W$ = change in work done

n = number of moles = 1.11 mol/s

R = Gas constant = 8.314 J/mol.K

T = temperature = 475 K

$P_1$ = initial pressure = 100 kPa

$P_2$ = final pressure = 50 kPa

Putting values in above equation, we get:

$\Delta W=1.11mol/s\times 8.314J\times 475K\times \ln (\frac{100}{50})\\\\\Delta W=3038.45J/s=3.038kJ/s=3.038kW$

Calculating the heat flow, we use equation 1, we get:

[ex]\Delta q=3.038kW[/tex]

Now, calculating the rate of lost work, we use the equation:

$\text{Rate of lost work}=\Delta W-\text{Power produced}\\\\\text{Rate of lost work}=(3.038-2)kW\\\text{Rate of lost work}=1.038kW$

Hence, the rate of heat flow is 3.038 kW and the rate of lost work is 1.038 kW.

4 0

3 years ago

What are the smallest sub atomic structure

Anton [14]

Answer:

Electrons

Explanation:

In an atom there would be three subatomic particles: Neutrons, electrons, protons. The smallest and lightest in terms of mass is electrons. This is because the nucleus is comprised of the protons and the neutrons, these have a greater mass than electrons as electrons has very little mass that can considered to be 0.

7 0

3 years ago

What is the balanced equation for the reaction of aqueous cesium sulfate and aqueous barium perchlorate?

Aleksandr-060686 [28]

Answer:

The balanced chemical reaction is given as:

$Cs_2SO_4(aq)+Ba(ClO_4)_2(aq)\rightarrow BaSO_4(s)+2CsClO_4(aq)$

Explanation:

When aqueous cesium sulfate and aqueous barium perchlorate are mixed together it gives white precipitate barium sulfate and aqueous solution od cesium perchlorate.

The balanced chemical reaction is given as:

$Cs_2SO_4(aq)+Ba(ClO_4)_2(aq)\rightarrow BaSO_4(s)+2CsClO_4(aq)$

According to reaction, 1 mole of cesium sulfate reacts with 1 mole of barium perchlorate to give 1 mole of a white precipitate of barium sulfate and 2 moles of cesium perchlorate.

3 0

3 years ago

a sample of compound determined to contain 1.71 g C and 0.287 g H. The corresponding empirical formula is

fiasKO [112]

Answer: The empirical formula is $CH_2$ .