Answer:
Equation of reaction:
a) 2HCl + Ba(OH)2 ==> CaCl2 + 2H2O
b) Molarity of base = 0.042 M.
Explanation:
Using titration equation
CAVA/CBVB = NA/NB
Where NA is the number of mole of acid = 2
NB is the number of mole of base = 1
CA is the molarity of acid =0.15M
CB is the molarity of base = to be calculated
VA is the volume of acid = 25 ml
VB is the volume of base = 44.45mL
Substituting
0.15×25/CB×44.45 = 2/1
Therefore CB =0.15×25×1/44.45×2
CB = 0.042 M.
You can use a graduated cylinder.
Answer:
a) The equilibrium will shift in the right direction.
b) The new equilibrium concentrations after reestablishment of the equilibrium :
![[SbCl_5]=(0.370-x) M=(0.370-0.0233) M=0.3467 M](https://tex.z-dn.net/?f=%5BSbCl_5%5D%3D%280.370-x%29%20M%3D%280.370-0.0233%29%20M%3D0.3467%20M)
![[SbCl_3]=(6.98\times 10^{-2}+x) M=(6.98\times 10^{-2}+0.0233) M=0.0931 M](https://tex.z-dn.net/?f=%5BSbCl_3%5D%3D%286.98%5Ctimes%2010%5E%7B-2%7D%2Bx%29%20M%3D%286.98%5Ctimes%2010%5E%7B-2%7D%2B0.0233%29%20M%3D0.0931%20M)
![[Cl_2]=(6.98\times 10^{-2}+x) M=(6.98\times 10^{-2}+0.0233) M=0.0931 M](https://tex.z-dn.net/?f=%5BCl_2%5D%3D%286.98%5Ctimes%2010%5E%7B-2%7D%2Bx%29%20M%3D%286.98%5Ctimes%2010%5E%7B-2%7D%2B0.0233%29%20M%3D0.0931%20M)
Explanation:

a) Any change in the equilibrium is studied on the basis of Le-Chatelier's principle.
This principle states that if there is any change in the variables of the reaction, the equilibrium will shift in the direction to minimize the effect.
On increase in amount of reactant

If the reactant is increased, according to the Le-Chatlier's principle, the equilibrium will shift in the direction where more product formation is taking place. As the number of moles of
is increasing .So, the equilibrium will shift in the right direction.
b)

Concentration of
= 0.195 M
Concentration of
= 
Concentration of
= 
On adding more
to 0.370 M at equilibrium :

Initially
0.370 M
At equilibrium:
(0.370-x)M
The equilibrium constant of the reaction = 

The equilibrium expression is given as:
![K_c=\frac{[SbCl_3][Cl_2]}{[SbCl_5]}](https://tex.z-dn.net/?f=K_c%3D%5Cfrac%7B%5BSbCl_3%5D%5BCl_2%5D%7D%7B%5BSbCl_5%5D%7D)

On solving for x:
x = 0.0233 M
The new equilibrium concentrations after reestablishment of the equilibrium :
![[SbCl_5]=(0.370-x) M=(0.370-0.0233) M=0.3467 M](https://tex.z-dn.net/?f=%5BSbCl_5%5D%3D%280.370-x%29%20M%3D%280.370-0.0233%29%20M%3D0.3467%20M)
![[SbCl_3]=(6.98\times 10^{-2}+x) M=(6.98\times 10^{-2}+0.0233) M=0.0931 M](https://tex.z-dn.net/?f=%5BSbCl_3%5D%3D%286.98%5Ctimes%2010%5E%7B-2%7D%2Bx%29%20M%3D%286.98%5Ctimes%2010%5E%7B-2%7D%2B0.0233%29%20M%3D0.0931%20M)
![[Cl_2]=(6.98\times 10^{-2}+x) M=(6.98\times 10^{-2}+0.0233) M=0.0931 M](https://tex.z-dn.net/?f=%5BCl_2%5D%3D%286.98%5Ctimes%2010%5E%7B-2%7D%2Bx%29%20M%3D%286.98%5Ctimes%2010%5E%7B-2%7D%2B0.0233%29%20M%3D0.0931%20M)
Antimony,carbon sodium gallium