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statuscvo [17]
3 years ago
9

The relation between stability and solubility​

Chemistry
1 answer:
Alex17521 [72]3 years ago
3 0

Answer:

2

Nobody is able to foresee the solubility of a product. There are some experimental rules, but they all have exceptions, that nobody is able to explain.

Just have a look on the Calcium salts made with the halogens (F, Cl, Br, I). There is a nice analogy among Cl, Br and I, but not F. Look ! The Calcium chloride CaCl2, bromide CaBr2 and iodide CaI2 are all extremely soluble in water. They are all soluble in less than their weight of water. But calcium fluoride CaF2 is among the least soluble product on Earth. The principal mineral for Fluoride is CaF2, and it can be found everywhere at the surface of the Earth. If this mineral would have been at least a little soluble in water, the rains would have washed away this mineral in the geological times. Why is there such a huge difference between calcium fluoride and the other halogenides ? Nobody knows !

Another example. Potassium perchlorate is the only potassium salt which is very weakly soluble in water. By comparison, Sodium perchlorate is extremely soluble in water. Why? Another example: the number of Silver compounds which are soluble in water is limited. In organic solvents, it is even worse. But the Handbook of Chemistry and Physics says that Silver perchlorate is soluble in toluene. Why? Nobody knows.

From time to time there are articles published in journals like the Journal of Chemical Education. The author is proud of displaying a theory filled with new parameters, for explaining the solubility of quite a lot of chemicals. But there are always exceptions, that he regrets not to be able to explain.

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8.43g of CaCl2·2H2O is dissolved in 40.0g of H2O. What is the molality of the solution? (Note that the H2O in the CaCl2·2H2O mus
lara31 [8.8K]

Answer:

[CaCl₂·2H₂O] = 1.43 m

Explanation:

Molality is mol of solute / kg of solvent.

Mass of solvent = 40 g

Let's convert g to kg → 40 g / 1000 = 0.04 kg

Let's determine the moles of solute (mass / molar mass)

8.43 g / 146.98 g/mol = 0.057 mol

Molality = 0.057 mol / 0.04 kg → 1.43

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3 years ago
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Answer:

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Which pH value represents a solution with the lowest OHM<br> ion concentration?
Arlecino [84]

pH value 1 represents a solution with the lowest OH⁻ion concentration.

<u>Explanation:</u>

pH is given by the expression as the negative logarithm to the base 10 of the concentration of hydrogen ions.

pH = -log₁₀[H⁺]

If the pH is lower than 7, pH < 7 then it is acidic

If the pH = 7, then it is neutral

If the pH > 7, then it is basic

If pH is 1 then the solution is showing mostly acidic character,which is least basic in its character.

So if the pH is 1, which is most acidic and least basic solution that is lowest OH⁻ ion concentration.

7 0
3 years ago
how many grams of calcium sulfate are produced from 10 grams of calcium nitrate and how many grams of calcium sulfate are produc
AlekseyPX

Answer:  8.30 g of calcium sulfate are produced from 10 grams of lithium sulfate.

Explanation:

To calculate the moles :

\text{Moles of solute}=\frac{\text{given mass}}{\text{Molar Mass}}    

\text{Moles of} Ca(NO_3)_2=\frac{10g}{164g/mol}=0.061moles

\text{Moles of} Li_2SO_4=\frac{10g}{110g/mol}=0.091moles

Ca(NO_3)_2+Li_2SO_4\rightarrow 2LiNO_3+CaSO_4  

According to stoichiometry :

1 mole of Ca(NO_3)_2 require = 1 mole of Li_2SO_4

Thus 0.061 moles of Ca(NO_3)_2 will require=\frac{1}{1}\times 0.061=0.061moles  of Li_2SO_4

Thus Ca(NO_3)_2 is the limiting reagent as it limits the formation of product and Li_2SO_4 is the excess reagent.

As 1 mole of Ca(NO_3)_2 give = 1 mole of CaSO_4

Thus 0.061 moles of Ca(NO_3)_2 give =\frac{1}{1}\times 0.061=0.061moles  of CaSO_4

Mass of CaSO_4=moles\times {\text {Molar mass}}=0.061moles\times 136g/mol=8.30g

Thus 8.30 g of calcium sulfate are produced from 10 grams of lithium sulfate.

6 0
3 years ago
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