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taurus [48]
3 years ago
13

Question 044 Which of the following sequences converts 2-methylpropene and sodium acetylide into 3-methylbutanal? 1) HBr; 2) NaC

CH; 3) O3; 4) DMS 1) NaCCH; 2) H2/Ni2B; 3) O3; 4) DMS 1) HBr, ROOR; 2) NaCCH; 3) H2/Ni2B 4) O3; 5) DMS 1) HBr, ROOR; 2) NaCCH; 3) O3; 4) H2O 1) HBr; 2) NaCCH; 3) O3; 4) H2O
Chemistry
2 answers:
Minchanka [31]3 years ago
8 0

Answer:

1) HBr; 2) NaCCH; 3) O3; 4) H2O

Explanation:

The first step is formation of alkyl halide followed by reaction with sodium acetylide, to form 3-methylbutene, which is then followed by oxidation reaction with O3& H2O to 3-methylbutanal

Kruka [31]3 years ago
6 0

Answer:

The sequence of reagents' incorporation for the conversion of 2-methylpropene into 3-methylbutanal is <u>option (C.):</u>

1. HBr,ROOR ; 2.  NaCCH,H_{2}/Ni_{2}B ; 3. O_{3}, DMS

Explanation:

The summary of this reaction's mechanism is as follows:

  • <em>Radical hydro-halogenation</em> of 2-methylpropene through a technique known as <em>"peroxide effect"</em> in which the HBr addition causes free radical formation of the alkene
  • <em>Nucleophilic SN2 substitution </em>reaction (acetylide)
  • <em>Hydrogenation</em>
  • <em>Ozonolysis of the alkene</em>: after the addition reaction, the intermediate ozonide is converted to aldehyde using dimethyl sulfide (DMS)
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What is the value of the equilibrium constant at 25 oC for the reaction between the pair: Ag(s) and Ni2+(aq) to give Ni(s) and A
rusak2 [61]

Answer: 3\times 10^{35}

Explanation:

The balanced chemical equation will be:

2Ag(s)+Ni^{2+}(aq)\rightarrow 2Ag^{+}(aq)+Ni(s)

Here Ag undergoes oxidation by loss of electrons, thus act as anode. Nickel undergoes reduction by gain of electrons and thus act as cathode.

E^0=E^0_{cathode}- E^0_{anode}

Where both E^0 are standard reduction potentials.

E^0_{[Ag^{+}/Mg]}=+0.80V

E^0_{[Ni^{2+}/Ni]}=-0.25V

E^0=E^0_{[Ni^{2+}/Ni]}- E^0_{[Ag^{+}/Ag]}

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The standard emf of a cell is related to Gibbs free energy by following relation:

\Delta G=-nFE^0

\Delta G = gibbs free energy  

n= no of electrons gained or lost  =?

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\Delta G=-2\times 96500\times (-1.05)=202650J

The Gibbs free energy is related to equilibrium constant by following relation:

\Delta G=-2.303RTlog K

R = gas constant = 8.314 J/Kmol

T = temperature in kelvin =25^0C=25+273=298K

K = equilibrium constant

\Delta G=-2.303RTlog K

+202650=-2.303\times 8.314\times 298\times logK

K=3\times 10^{35}

Thus the value of the equilibrium constant at 25^0C is 3\times 10^{35}

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3 years ago
Which statement describes the charge of an
qwelly [4]
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F(x)=-1/x
g(x)=√(3x-9)

Domain of (f/g)(x):  ??

1We find out the domain of f(x):
f(x) is a rational function, therefore can take real values if the denominator is not ("0"), therefore the domain of f, will be all values excpet "0"
Domain of  f: (-∞,0)U(0,+∞); 


                                                          o
----------------------------------------------O-------------------------------------------
←-------- -∞                                                               +∞           ----------→


g(x) is a radical square root  function, therefore the radicand have to be greater than o equal to "0"
3x-9≥0
3x≥9
x≥3

                                                         3
.........................................................Ф--------------------------------
←--------- - ∞                                                        +∞ -----------→
          
(f/g)(x) = (-1/x) / (√(3x-9)) is a rational function with a square root in the denominator,also the square root don´t take the value of "0";
Therefore:
3x-9>0
3x>9
x>3

The domain of the function (f/g)(x) only can take the values found in all three domains at once.
                                                            3
............................................................0---------------------------------
←--------- -∞                                                          +∞-------------→

Answer: (3,+∞)
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HACTEHA [7]

Answer:

3 moles

Explanation:

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we are given 36 g of C-12. So,

12 g of C-12 = 1 mole

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36 g of C-12 = 3 mole

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