They have to form a chemical bond in order to brake them down first
One of the causes of polarity is the unequal forces of the dipole forces due to differences in electronegativity. The more electronegative molecule tend to attract electrons, hence the polarity arrows point towards it. The electronegativity of Phosphorus and Fluorine is 2.19 and 3.98, respectively. Thus, it points outward towards the fluorine atoms.
500 meters is the correct answer :)
