Answer:
ai) Rate law, ![Rate = k [CH_3 Cl] [Cl_2]^{0.5}](https://tex.z-dn.net/?f=Rate%20%3D%20k%20%5BCH_3%20Cl%5D%20%5BCl_2%5D%5E%7B0.5%7D)
aii) Rate constant, k = 1.25
b) Overall order of reaction = 1.5
Explanation:
Equation of Reaction:

If
, the rate of backward reaction is given by:
![Rate = k [A]^{a} [B]^{b}\\k = \frac{Rate}{ [A]^{a} [B]^{b}}\\k = \frac{Rate}{ [CH_3 Cl]^{a} [Cl_2]^{b}}](https://tex.z-dn.net/?f=Rate%20%3D%20k%20%5BA%5D%5E%7Ba%7D%20%5BB%5D%5E%7Bb%7D%5C%5Ck%20%3D%20%5Cfrac%7BRate%7D%7B%20%5BA%5D%5E%7Ba%7D%20%5BB%5D%5E%7Bb%7D%7D%5C%5Ck%20%3D%20%5Cfrac%7BRate%7D%7B%20%5BCH_3%20Cl%5D%5E%7Ba%7D%20%5BCl_2%5D%5E%7Bb%7D%7D)
k is constant for all the stages
Using the information provided in lines 1 and 2 of the table:
![0.014 / [0.05]^a [0.05]^b = 00.029/ [0.100]^a [0.05]^b\\0.014 / [0.05]^a [0.05]^b = 00.029/ [2*0.05]^a [0.05]^b\\0.014 / = 0.029/ 2^a\\2^a = 2.07\\a = 1](https://tex.z-dn.net/?f=0.014%20%2F%20%5B0.05%5D%5Ea%20%5B0.05%5D%5Eb%20%3D%2000.029%2F%20%5B0.100%5D%5Ea%20%5B0.05%5D%5Eb%5C%5C0.014%20%2F%20%5B0.05%5D%5Ea%20%5B0.05%5D%5Eb%20%3D%2000.029%2F%20%5B2%2A0.05%5D%5Ea%20%5B0.05%5D%5Eb%5C%5C0.014%20%2F%20%3D%200.029%2F%202%5Ea%5C%5C2%5Ea%20%3D%202.07%5C%5Ca%20%3D%201)
Using the information provided in lines 3 and 4 of the table and insering the value of a:
![0.041 / [0.100]^a [0.100]^b = 0.115 / [0.200]^a [0.200]^b\\0.041 / [0.100]^a [0.100]^b = 0.115 / [2 * 0.100]^a [2 * 0.100]^b\\](https://tex.z-dn.net/?f=0.041%20%2F%20%5B0.100%5D%5Ea%20%5B0.100%5D%5Eb%20%3D%200.115%20%2F%20%5B0.200%5D%5Ea%20%5B0.200%5D%5Eb%5C%5C0.041%20%2F%20%5B0.100%5D%5Ea%20%5B0.100%5D%5Eb%20%3D%200.115%20%2F%20%5B2%20%2A%200.100%5D%5Ea%20%5B2%20%2A%200.100%5D%5Eb%5C%5C)
![0.041 = 0.115 / [2 ]^a [2]^b\\ \[[2 ]^a [2]^b = 0.115/0.041\\ \[[2 ]^a [2]^b = 2.80\\\[[2 ]^1 [2]^b = 2.80\\\[[2]^b = 1.40\\b = \frac{ln 1.4}{ln 2} \\b = 0.5](https://tex.z-dn.net/?f=0.041%20%3D%200.115%20%2F%20%5B2%20%5D%5Ea%20%5B2%5D%5Eb%5C%5C%20%5C%5B%5B2%20%5D%5Ea%20%5B2%5D%5Eb%20%3D%200.115%2F0.041%5C%5C%20%5C%5B%5B2%20%5D%5Ea%20%5B2%5D%5Eb%20%3D%202.80%5C%5C%5C%5B%5B2%20%5D%5E1%20%5B2%5D%5Eb%20%3D%202.80%5C%5C%5C%5B%5B2%5D%5Eb%20%3D%201.40%5C%5Cb%20%3D%20%5Cfrac%7Bln%201.4%7D%7Bln%202%7D%20%5C%5Cb%20%3D%200.5)
The rate law is: ![Rate = k [CH_3 Cl] [Cl_2]^{0.5}](https://tex.z-dn.net/?f=Rate%20%3D%20k%20%5BCH_3%20Cl%5D%20%5BCl_2%5D%5E%7B0.5%7D)
The rate constant
then becomes:
![k = 0.014 / ( [0.050] [0.050]^(0.5) )\\k = 1.25](https://tex.z-dn.net/?f=k%20%3D%200.014%20%2F%20%28%20%5B0.050%5D%20%5B0.050%5D%5E%280.5%29%20%29%5C%5Ck%20%3D%201.25)
b) Overall order of reaction = a + b
Overall order of reaction = 1 + 0.5
Overall order of reaction = 1.5
What about it do you want answered
Answer:
101.50 g H₂O
Explanation:
The mole ratio of HNO₃ and H₂O is 6 : 2
Hence, 16.9 moles of HNO₃ will produce = 2/6×16.9 = 5.63 moles of H₂O
Also,
Mass = Moles × M.Mass
Mass = 5.63 mol × 18.02 g/mol
Mass = 101.50 g H₂O
Answer:
187.34 atm
Explanation:
From the question,
PV = nRT.................. Equation 1
Where P = Pressure, V = Volume, n = number of mole, R = molar gas constant, T = Temperature.
make P the subject of the equation
P = nRT/V.............. Equation 2
n = mass(m)/molar mass(m')
n = m/m'............... Equation 3
Substitute equation 3 into equation 2
P = (m/m')RT/V............ Equation 4
Given: m = 46 g, T = 25°C = (25+273) = 298 K, V = 3.00 L
Constant: m' = 2 g/mol, R = 0.082 atmL/K.mol
Substitute these values into equation 4
P = (46/2)(0.082×298)/3
P = (23×0.082×298)/3
P = 187.34 atm
Answer:
0.50 M
Explanation:
Given data
- Mass of sodium sulfate (solute): 7.1 g
- Volume of solution: 100 mL
Step 1: Calculate the moles of the solute
The molar mass of sodium sulfate is 142.04 g/mol. The moles corresponding to 7.1 grams of sodium sulfate are:

Step 2: Convert the volume of solution to liters
We will use the relation 1 L = 1000 mL.

Step 3: Calculate the molarity of the solution
