Find the ph of a 0.250 m solution of nac2h3o2. (the ka value of hc2h3o2 is 1.80×10−5). express your answer numerically to four s

Question

CaHeK987 [17]

3 years ago

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Find the ph of a 0.250 m solution of nac2h3o2. (the ka value of hc2h3o2 is 1.80×10−5). express your answer numerically to four s

ignificant figures.

Chemistry

1 answer:

Slav-nsk [51] · Answer 1 · 2022-01-20T19:43:00+03:00

Answer is: pH value of solution of NaC₂H₃O₂ is 9.07.
Chemical reaction: C₂H₃O₂⁻ + H₂O ⇄ HC₂H₃O₂ + OH⁻.
Ka(HC₂H₃O₂) = 1,8·10⁻⁵.
Ka · Kb = Kw.
1,8·10⁻⁵ mol/dm³ · Kb = 1·10⁻¹⁴ mol²/dm⁶; the ionic product of water at 25°C.
Kb(C₂H₃O₂⁻) = 1·10⁻¹⁴ mol²/dm⁶ ÷ 1,8·10⁻⁵ mol/dm³.
Kb(C₂H₃O₂⁻) = 5,56·10⁻¹⁰ mol/dm³.
c(C₂H₃O₂⁻) = 0,25 M.
[OH⁻] = [HC₂H₃O₂] = x.
[C₂H₃O₂⁻] = 0,25 M - x.
Kb = [OH⁻] · [HC₂H₃O₂] / [C₂H₃O₂⁻].
5,56·10⁻¹⁰ = x² / (0,25 M -x).
Solve quadratic equation: x = [OH⁻] = 0,0000118 M.
pOH = -log[OH⁻] = -log(0,0000118M) = 4,93.
pH + pOH = 14.
pH = 14 - 4,93 = 9,07.