Answer is: 7,826 kg of cryolite.
Chemical reaction: Al₂O₃ + 6NaOH + 12HF → 2Na₃AlF₆ + 9H₂<span>O.
m(</span>Al₂O₃) = 12,1 kg = 12100 g.
n(Al₂O₃) = m(Al₂O₃) ÷ M(Al₂O₃).
n(Al₂O₃) = 12100 g ÷ 101,96 g/mol = 111,86 mol; limiting reactant.
m(NaOH) = 60,4 kg = 60400 g.
n(NaOH) = 60400 g ÷ 40 g/mol.
n(NaOH) = 1510 mol.
m(HF) = 60,4 kg = 60400 g.
n(HF) = 60400 g ÷ 20 g/mol = 3020 mol.
From chemical reaction: n(Al₂O₃) : n(Na₃AlF₆) = 6 : 2.
n(Na₃AlF₆) = 2 ·111,86 mol ÷ 6 = 37,28 mol.
m(Na₃AlF₆) = 37,28 mol · 209,94 g/mol.
m(Na₃AlF₆) = 7826,56 g = 7,826 kg.
Explanation:
To delineate the the nature of the bonds that would be formed between the two elements, let us first write the electronic configuration of the two species;
Be = 2, 2
F = 2, 7
Beryllium is a metal with two valence electrons whereas fluorine is a halogen with seven valence electrons.
When Be loses two electrons it becomes isoelectronic with He;
Be → Be²⁺ + 2e⁻
Also, when fluorine gains an electron, it becomes isoelectronic with Ne;
F + e⁻ → F⁻
This loss and gain of electrons between the two elements creates an electrostatic attraction them and they enter into an electrovalent bond.
Hence;
Be²⁺ + 2F⁻ → BeF₂
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Answer:
28.7664 kJ /mol
Explanation:
The expression for Clausius-Clapeyron Equation is shown below as:
Where,
P is the vapor pressure
ΔHvap is the Enthalpy of Vaporization
R is the gas constant (8.314×10⁻³ kJ /mol K)
c is the constant.
The graph of ln P and 1/T gives a slope of - ΔHvap/ R and intercept of c.
Given :
Slope = -3.46×10³ K
So,
- ΔHvap/ R = -3.46×10³ K
<u>ΔHvap = 3.46×10³ K × 8.314×10⁻³ kJ /mol K = 28.7664 kJ /mol</u>
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Answer:
1400KJ/mol⁻¹
Explanation:
Amount of heat required can be found by:
Q = m × c × ΔT
<em>Where m is the mass, c is the specific heat capacity (4.2KJ for water) and ΔT is the change in temperature.</em>
Q = 24 × 4.2 × (23 - 9)
= 24 × 4.2 × 14
= 1411.2KJ/mol⁻¹
= <u>1400KJ/mol⁻¹</u> (to 2 significant figures)
