Answer:
1) HCl contains the Cl^- which is a good nucleophile
2) 2-methyl-2- heptanol > 2-heptanol > 1-heptanol
3) see image attached
Explanation:
If the dehydration of alcohols is carried out using HCl, the chloride ion which is a good nucleophile will attack the substrate to yield an undesirable product.
The dehydration of alcohols is an E1 reaction. Recall that the ease of E1 reaction increases in the order 3°> 2°> 1°. Hence, 2-methyl-2- heptanol forms a tertiary carbocation intermediate during dehydration and has the greatest ease of dehydration.
The three products formed during the dehydration of 3,3-dimethyl-2-butanol are shown in the image attached. Two out of the three are formed by rearrangement reactions.
Answer: A
Explanation: the only way to turn it from blue to yellow is to mix it with an acidic solution.
Answer:
Four substitution products are obtained. The carbocation that forms can react with either nucleophile (H2O or CH3OH) from either the top or bottom side of the molecule
Explanation:
An SN1 reaction usually involves the formation of a carbocation in the slow rate determining step. This carbocation is now attacked by a nucleophile in a subsequent fast step to give the desired product.
However, the product is obtained as a racemic mixture because the nucleophile may attack from the top or bottom of the carbocation hence both attacks are equally probable.
The attacking nucleophile in this case may be water or CH3OH
Explanation:
nnbbnmkmknn bnnnbbtbbbbn' nn' t
Hept for 7, hence the number is seven.
