Answer:
It means the chemical entity is a radical
Explanation:
When we talk of unsaturation, we are referring to the number of pi-bonds in a chemical entity. The alkane, alkene and alkyne organic family are used to as common examples to explain the term unsaturation.
While alkynes have 3 bonds, it must be understood that they have 2 pi bonds only and as such their degree of saturation is two.
In the case of an alkene, there is only one single pi bond and as such the degree of unsaturation is 1.
Now in this case, we have a fractional 0.5 degree of unsaturation alongside the 3 to make a total of 3.5. So what’s the issue here?
The fractional part shows that the chemical entity we are dealing with here is a radical. While the integer 3 shows that there are 3 pi-bonds, the half pi bond remaining tells us that there is a missing electron on one of the atoms involved in the chemical bonding and as such, the 1/2 extra degree of unsaturation tends to tell us this.
Kindly recall that a radical is a chemical entity within which we have at the least an unpaired electron.
Answer:
0.007 mol
Explanation:
We can solve this problem using the ideal gas law:
PV = nRT
where P is the total pressure, V is the volume, R the gas constant, T is the temperature and n is the number of moles we are seeking.
Keep in mind that when we collect a gas over water we have to correct for the vapor pressure of water at the temperature in the experiment.
Ptotal = PH₂O + PO₂ ⇒ PO₂ = Ptotal - PH₂O
Since R constant has unit of Latm/Kmol we have to convert to the proper unit the volume and temperature.
P H₂O = 23.8 mmHg x 1 atm/760 mmHg = 0.031 atm
V = 1750 mL x 1 L/ 1000 mL = 0.175 L
T = (25 + 273) K = 298 K
PO₂ = 1 atm - 0.031 atm = 0.969 atm
n = PV/RT = 0.969 atm x 0.1750 L / (0.08205 Latm/Kmol x 298 K)
n = 0.007 mol
Answer:
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Explanation: