Answer:
Explanation:
exothermic reactions involve release of heat whereas endothermic reaction involve absorption of heat.
Answer: the coefficient of volume expansion of glass = 0.86/(1000 * 52) = 0.00001654 per degree.
Explanation:
Original volume of mercury = 1000 cm3.
The final volume of mercury considering its volume expansion quotient = 1000 + 1000*(1.8*10^-4 *52) = 1000 + 9.36 = 1009.36 cm^3
Considering the glass as a non expanding substance, the complete excess volume of 9.36 cm3 of mercury should have overflown the container, but due to the expansion of glass, the capacity of mercury containment increases and so a lesser amount of mercury flows out.
The amount of mercury that actually flowed out = 8.50 cm3.
So, the expansion of the glass container = 9.36-8.50 = 0.86 cm3.
Using the formula for coefficient of expansion,
coefficient of volume expansion of glass = 0.86/(1000 * 52) = 0.00001654 per degree.
<u>Answer:</u> The rate law of the reaction is ![\text{Rate}=k[HgCl_2][C_2O_4^{2-}]^2](https://tex.z-dn.net/?f=%5Ctext%7BRate%7D%3Dk%5BHgCl_2%5D%5BC_2O_4%5E%7B2-%7D%5D%5E2)
<u>Explanation:</u>
Rate law is defined as the expression which expresses the rate of the reaction in terms of molar concentration of the reactants with each term raised to the power their stoichiometric coefficient of that reactant in the balanced chemical equation.
For the given chemical equation:

Rate law expression for the reaction:
![\text{Rate}=k[HgCl_2]^a[C_2O_4^{2-}]^b](https://tex.z-dn.net/?f=%5Ctext%7BRate%7D%3Dk%5BHgCl_2%5D%5Ea%5BC_2O_4%5E%7B2-%7D%5D%5Eb)
where,
a = order with respect to 
b = order with respect to 
Expression for rate law for first observation:
....(1)
Expression for rate law for second observation:
....(2)
Expression for rate law for third observation:
....(3)
Expression for rate law for fourth observation:
....(4)
Dividing 2 from 1, we get:

Dividing 2 from 3, we get:

Thus, the rate law becomes:
![\text{Rate}=k[HgCl_2]^1[C_2O_4^{2-}]^2](https://tex.z-dn.net/?f=%5Ctext%7BRate%7D%3Dk%5BHgCl_2%5D%5E1%5BC_2O_4%5E%7B2-%7D%5D%5E2)
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The answer is strong winds