Answer:
Acetylide , Enol ,aldehydes, tautomers, alkynes , Hydroboration, Keto
Explanation:
Reset <u>Acetylide</u> anions are strong nucleophiles that open epoxide rings by an SN2 mechanism. <u>Enol </u>tautomers have an O-H group bonded to a C=C. <u>aldehydes </u>are formed from terminal alkynes with the addition of water using BH3 then H2O2. <u>tautomers</u> are constitutional isomers that differ in the location of a double bond and a hydrogen and exist in an equilibrium with each other. <u>alkynes</u> are compounds that contain a carbon-carbon triple bond. <u>Hydroboration</u> of a terminal alkyne adds BH₂ to the less substituted, terminal carbon.<u> Keto</u> tautomers have a C=O and an additional C-H bond.
Answer:
∴ΔH₂ = - 12,258 KJ
Explanation:
Enthalpy:
Enthalpy is a property of a thermodynamic system. Enthalpy of a system is equal to the sum of internal energy of the system and presser times volume of the system.
The heat absorbes or releases in a closed system is the change of enthalpy of the system.
Given reactions are:
Reaction 1: C₃H₈(g)+5O₂(g)→ 3CO₂(g)+4H₂O, ΔH₁= - 2043 KJ
Reaction 2: 6C₃H₈(g)+30 O₂(g)→ 18 CO₂(g)+24 H₂O, ΔH₂=?
Take a look at reaction 1 and reaction 2, the only difference is that 1 molecule of C₃H₈ is combusted in reaction 1 and 6 molecules of C₃H₈ is combusted in reaction 2.
We can think the reaction 2 as occurring 6 different container and each containers contains 1 molecule of C₃H₈. The enthalpy is an extensive property. Total enthapy of the 6 containers is = 6×(-2043 KJ)
= - 12,258 KJ
∴ΔH₂ = - 12,258 KJ
To determine the volume of both concentration of vinegar, we need to set up two equations since we have two unknowns.
For the first equation, we do a mass balance:
mass of 100% vinegar + mass of 13% vinegar = mass of 42% vinegar
Assuming they have the same densities, then we can write this equation in terms of volume.
V(100%) + V(13%) = V(42%)
we let x = V(100%)
y = V(13%)
x + y = 150
For the second equation, we do a component balance:
1.00x + .13y = 150(.42)
x + .13y = 63
The two equations are
x + y = 150
x + .13y = 63
Solving for x and y,
x = 50
y = 100
Therefore, you need to mix 50 mL of the 100% vinegar and 100 mL of the 13% vinegar.
