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3 years ago

What happens to the volume of a gas in a closed container if the temperature increases, but the pressure remains the same? Why?

Chemistry

1 answer:

labwork [276]3 years ago

3 0

Answer:

Volume will goes to increase.

Explanation:

The given problem will be solve through the Charles Law.

According to this law, The volume of given amount of a gas is directly proportional to its temperature at constant number of moles and pressure.

Mathematical expression:

V₁/T₁ = V₂/T₂

V₁ = Initial volume

T₁ = Initial temperature

V₂ = Final volume

T₂ = Final temperature

So when the temperature goes to increase the volume of gas also increase. Higher temperature increase the kinetic energy and molecules move randomly every where in given space so volume increase.

Now we will put the suppose values in formula.

V₁/T₁ = V₂/T₂

V₂ = V₁T₂/T₁

V₂ = 4.5 L × 348 K / 298 k

V₂ = 1566 L.K / 298 K

V₂ = 5.3 L

Hence prove that volume increase by increasing the temperature.

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The Handbook of Chemistry and Physics gives solubilities of the following compounds in grams per 100 mL water. Because these com

Elanso [62]

Answer:

(a) $Ksp=4.50x10^{-7}$

(b) $Ksp=1.55x10^{-6}$

(d) $Ksp=1.05x10^{-22}$

Explanation:

Hello,

In this case, given the solubility of each salt, we can compute their molar solubilities by using the molar masses. Afterwards, by using the mole ratio between ions, we can compute the concentration of each dissolved and therefore the solubility product:

(a) $BaSeO_4(s)\rightleftharpoons Ba^{2+}(aq)+SeO_4^{2-}(aq)$

$Molar\ solubility=\frac{0.0188g}{100mL} *\frac{1mol}{280.3g}*\frac{1000mL}{1L}=6.7x10^{-4}\frac{mol}{L}$

In such a way, as barium and selenate ions are in 1:1 molar ratio, they have the same concentration, for which the solubility product turns out:

$Ksp=[Ba^{2+}][SeO_4^{2-}]=(6.7x10^{-4}\frac{mol}{L} )^2\\\\Ksp=4.50x10^{-7}$

(B) $Ba(BrO_3)_2(s)\rightleftharpoons Ba^{2+}(aq)+2BrO_3^{-}(aq)$

$Molar\ solubility=\frac{0.30g}{100mL} *\frac{1mol}{411.15g}*\frac{1000mL}{1L}=7.30x10^{-3}\frac{mol}{L}$

In such a way, as barium and bromate ions are in 1:2 molar ratio, bromate ions have twice the concentration of barium ions, for which the solubility product turns out:

$Ksp=[Ba^{2+}][BrO_3^-]^2=(7.30x10^{-3}\frac{mol}{L})(3.65x10^{-3}\frac{mol}{L})^2\\\\Ksp=1.55x10^{-6}$

$Molar\ solubility=\frac{0.038g}{100mL} *\frac{1mol}{289.35g}*\frac{1000mL}{1L}=1.31x10^{-4}\frac{mol}{L}$

In such a way, as ammonium, magnesium and arsenate ions are in 1:1:1 molar ratio, they have the same concentrations, for which the solubility product turns out:

$Ksp=[NH_4^+][Mg^{2+}][AsO_4^{3-}]^2=(1.31x10^{-4}\frac{mol}{L})^3\\\\Ksp=2.27x10^{-12}$

(D) $La_2(MoOs)_3(s)\rightleftharpoons 2La^{3+}(aq)+3MoOs^{2-}(aq)$

$Molar\ solubility=\frac{0.00179g}{100mL} *\frac{1mol}{1136.38g}*\frac{1000mL}{1L}=1.58x10^{-5}\frac{mol}{L}$

In such a way, as the involved ions are in 2:3 molar ratio, La ion is twice the molar solubility and MoOs ion is three times it, for which the solubility product turns out:

$Ksp=[La^{3+}]^2[MoOs^{-2}]^3=(2*1.58x10^{-5}\frac{mol}{L})^2(3*1.58x10^{-5}\frac{mol}{L})^3\\\\Ksp=1.05x10^{-22}$

Best regards.

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schepotkina [342]

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