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2 years ago

Which of the following alcohols will give a positive chromic acid test?

1 answer:

3 0

The answer is both B and C

positive chromic acid test is indicated by disappearance of orange colour from chromic ions and appearance of blue-green color from Chromium (iii) ion (reduction of chromium ion from CrO4 - to Cr3+)

positive chromic test indicated functional groups that can be oxidized.

cyclohexanol can be oxidized to become cyclohexanone

and pentan-3-ol can be oxidized to become pentan-3-one

hence both B and C will show positive chromic acid test

A) tert butanol although contains alcohol functional group, cannot be further oxidized as it is a tertiary alcohol

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Calculate the number of moles of gas in the following at STP: 45.6 L of H2 gas

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3 years ago

For each trial, compute the mol of titrant; (molarity x L) and keep the number of significant figures to 4.

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Answer:

Trial Number of moles

1 0.001249mol

2 0.001232mol

3 0.001187 mol

Explanation:

To calculate the number of moles of tritant you need its molarity.

Since the molarity is not reported, I will use 0.1000M (four significant figures), which is used in other similar problems.

Molarity is the concentration of the solution in number of moles of solute per liter of solution.

In this case the solute is NaOH.

The formula is:

$Molarity=\dfrac{\text{Number of moles of solute}}{\text{Volume of solution in liters}}$

Solve for the number of moles:

$\text{Number of moles}=Molarity\times Volume\text{ }in\text{ }liters$

Then, using the molarity of 0.1000M and the volumes for each trial you can calculate the number of moles of tritant.

Trial mL liters Number of moles

1 12.49 0.01249 0.01249liters × 0.1000M = 0.001249mol

2 12.32 0.01232 0.01232liters × 0.1000M = 0.001232mol

3 11.87 0.01187 0.01187liters × 0.1000M = 0.001187 mol

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